Citation: YANG Hong, WANG Hua-Hua, YANG Shu-Bao, ZHANG Hao, LIU Hai-Yang. Catalytic Styrene Oxidation by Iron Corroles Bearing Different Substituents[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 968-974. doi: 10.11862/CJIC.2015.141 shu

Catalytic Styrene Oxidation by Iron Corroles Bearing Different Substituents

1.
Department of Chemistry, South China University of Technology, Guangzhou 510641, China

Corresponding author: LIU Hai-Yang,
Received Date: 29 September 2014
Available Online: 10 January 2015
Fund Project: 国家自然科学基金(No.21273027)资助项目。 (No.21273027)

Four meso-substituted iron(Ⅳ) corroles having different number of pentafluorophenylor phenyl groups were synthesized and characterized by UV-Vis, NMR and MS. The catalytic styrene oxidation by these iron corroles using tert-butyl hydroperoxide (TBHP), iodosylbenzene (PhIO), hydrogen peroxide(H₂O₂) in acetonitrile was investigated. The effect of imidazole as axial ligand on the catalytic oxidation was also examined. The results indicate that the yields of the products depend on oxidants, catalysts and axial ligand. For TBHP, benzaldehyde is the major product. Styrene epoxide is the major product when using PhIOoxidant. All iron(Ⅳ) corroles studied cannot effectively catalyze styrene oxidation by using H₂O₂. Four iron corroles exhibit different activity order when using different oxidants, and the catalytic process may involve free radical and Fe(Ⅴ)-oxocorrole species. The axial coordination of F₁₅C-Feby imidazole gives 1:2 complexes. Also, axial ligand imidazole has different effect on the oxidation product distribution when using different oxidants.
- corroles;iron;catalytic oxidation;oxidants;styrene;axial ligand
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