Citation: DUAN Yan-Lin, MA Ran-Ran, CAO Ting-Ting, LIU Ting, LI Cheng-Juan, WANG Su-Na. Two Unusual 2D→3D Entanglement Networks Self-Assembled from a T-shaped Tricarboxylate Ligand: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1231-1238. doi: 10.11862/CJIC.2015.132 shu

Two Unusual 2D→3D Entanglement Networks Self-Assembled from a T-shaped Tricarboxylate Ligand: Syntheses, Structures and Properties

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Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: LI Cheng-Juan, WANG Su-Na,
Received Date: 10 February 2015
Available Online: 26 March 2015
Fund Project: 国家自然科学基金(No.20801025) (No.20801025)山东省自然科学基金(No.ZR2012BQ023) (No.ZR2012BQ023)山东省高等学校科技计划项目(No.J14LC10)资助。 (No.J14LC10)

Two Ni(Ⅱ)-organic frameworks, namely, {[Ni₃(BPT)₂(bpe)₂(H₂O)₆]·2DMF·7H₂O}_n (1) and {[Ni₃(BPT)₂(bpea)₂(H₂O)₆]·2DMF·5H₂O}_n (2) (H₃BPT = biphenyl-3,4',5-tricarboxylic acid, bpe = 1,2-bis(4-pyridyl)ethylene, bpea=1,2-bis(4-pyridyl)ethane, DMF=N,N-dimethylformamide), were solvothermally synthesized and characterized. In the two isostructural complexes, BPTligand and N-containing ligand bpea or bpe connect adjacent Ni centers to form a bilayer structure. The whole topology could be represented as (3,4)-connected (63)(65.8) with the tricarboxylate ligands and Ni atoms as 3-connected T-shaped and 4-connected tetrahedral nodes, respectively. Each bilayer polycatenates two other identical bilayers, giving rise to a 2D→3D polycatenating network with polyrotaxane moieties. Gas adsorptive measurements indicated compound 1 exhibited adsorption of CO₂ and N₂.
- metal-organic framework;polycatenating;biphenyl-3,4',5-tricarboxylic acid
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