Citation: NI Bang-Qing, HUANG Jiang-Lei, ZHANG Ping-Bo, FAN Ming-Ming. Al-MCM-41 Immobilized Ionic Liquids Catalysts Containing Double-Acid Active Sites for Biodiesel Production[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 961-967. doi: 10.11862/CJIC.2015.131 shu

Al-MCM-41 Immobilized Ionic Liquids Catalysts Containing Double-Acid Active Sites for Biodiesel Production

1.
School of Chemical and Material Engineering, Jiangnan University, the Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: FAN Ming-Ming,
Received Date: 30 January 2015
Available Online: 29 March 2015
Fund Project: 国家自然基金(No.21171057,21371059)与广东省自然基金(No.10351064101000000)资助项目。 (No.21171057,21371059)与广东省自然基金(No.10351064101000000)

The immobilized catalysts with double-acid active sites were synthesized by loading ionic liquids (ILs) on MCM-41 with different Si/Al molar ratios. The catalysts were characterized by XRD, FTIR, N₂ adsorption-desorption, thermogravimetric analysis and TEM, and the activities of catalysts were investigated by the transesterification of soybean oil with methanol for biodiesel synthesis as the probe reaction. The results demonstrated that the ionic liquids were successfully immobilized on the mesoporous molecular sieves. The catalysts could maintain their mesoporous structure and showed good catalytic performance in transesterification. The biodiesel yield was more than 90% under the condition of 30% ILs-loading, methanol to oil molar ratio of 36:1 and temperature at 140 ℃ for 5 h. The beneficial acid environment was created for the active component ILs by introducing Al to MCM-41, which greatly improved the catalytic performance of ILs. The ILs immobilized catalysts exhibited much higher activities in transesterification than the homogeneous ILs, and the ILs immobilized catalyst still yielded about 88% after four cycles.
- catalyst;mesoporous molecular sieves;ionic liquids;immobilize;biodiesel;transesterification
1. [1]
  [1] WU Qin(吴芹), CHEN He(陈和), HAN Ming-Han(韩明汉), et al. Chinese J. Catal.(催化学报), 2006,27(4):294-297
2. [2]
  [2] ZHANG Ping-Bo(张萍波), YANG Jing(杨静), FAN Ming-Ming(范明明), et al. Petrochem. Technol.(石油化工), 2011, 40(10):1133-1139
3. [3]
  [3] LI Jian-Fang(李健芳). Thesis for the Master of Dalian Univ-ersity of Technology(大连理工大学硕士论文). 2008.
4. [4]
  [4] ZHOU Hua-Feng(周华锋), YANG Yong-Jin(杨永进), ZHANG Jin-Song(张劲松). Chinese J. Mater. Res.(材料研究学报), 2009,23(2):199-204
5. [5]
  [5] Prasad M R, Madhavi G, Rao A R, et al. J. Porous Mater., 2006,13(1):81-94
6. [6]
  [6] Cristina G S, Ramón M T, Josefa M M R, et al. Appl. Catal. B: Environ., 2011,108-109:161-167
7. [7]
  [7] Brahmkhatri V, Patel A. Ind. Eng. Chem. Res., 2011,50(11): 6620-6628
8. [8]
  [8] CAO Ying-Yu(曹映玉), WANG Ya-Quan(王亚权), HAO Jin-Ku(郝金库). Chem. J. Chinese Universities(高等学校化学学报), 2011, 32(5):1138-1143
9. [9]
  [9] YANG Dong(杨栋), XIE Wen-Lei(谢文磊), WANG Jian-Long(王建龙). China Oils and Fats(中国油脂), 2010,35(9): 54-58
10. [10]
  [10] Olivier B H, Magna L, Morvan D. Appl. Catal. A: Gen., 2010, 373(1/2):1-56
11. [11]
  [11] Mehnert C P. Chem. Eur. J., 2004,11(1):50-56
12. [12]
  [12] Zhen B, Jiao Q Z, Zhang Y P, et al. Appl. Catal. A: Gen., 2012,445-446(1/2):239-245
13. [13]
  [13] Liang X Z. Ind. Eng. Chem. Res., 2014,53(44):17325-17332
14. [14]
  [14] Wu Z W, Li Z, Wu G M, et al. Ind. Eng. Chem. Res., 2014, 53(8):3040-3046
15. [15]
  [15] Liu F J, Wang L, Sun Q, et al. J. Am. Chem. Soc., 2012, 134(41):16948-16950
16. [16]
  [16] Liu F J, Zuo S F, Kong W P, et al. Green Chem., 2012,14 (5):1342-1349
17. [17]
  [17] ZHANG Ming-Jin(张铭金), YAO Rui-Ping(姚瑞平), ZHAO Hui-Zhong(赵惠忠), et al. J. Wuhan Univ. Sci. Technol.: Nat. Sci. Ed.(武汉科技大学学报:自然科学版), 2005,28(2): 154-157
18. [18]
  [18] Palani A, Pandurangan A. J. Mol. Catal. A: Chem., 2005, 226(1):129-134
19. [19]
  [19] FAN Ming-Ming(范明明), MAO Wei-Tao(毛炜陶), YANG Jing(杨静), et al. Chem. Ind. Eng. Prog.(化工进展), 2012, 31(6):1373-1378
20. [20]
  [20] WEN Yi(文毅). Thesis for the Master of Chongqing University (重庆大学硕士论文). 2013.
21. [21]
  [21] Zhang L, Cui Y D, Zhang C P, et al. Ind. Eng. Chem. Res., 2012,51(51):16590-16596
22. [22]
  [22] Song W M, Liu X, Jing T, et al. Chin. J. Chem. Eng., 2012, 20(5):900-905
23. [23]
  [23] Fuentes P D, Santamaría G J, Mérida R J, et al. J. Solid State Chem., 2006,179(7):2182-2189
24. [24]
  [24] GUO Jian-Ping(郭建平), YIN Du-Lin(尹笃林), GUO Jun(郭军). J. Xiangtan Normal Univ.: Nat. Sci. Ed.(湘潭师范学院学报:自然科学版), 2001,23(3):65-68
25. [25]
  [25] González F, Pesquera C, Perdigón A, et al. Appl. Surf. Sci., 2009,255(17):7825-7830
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
6. [6]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
7. [7]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
8. [8]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
11. [11]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
12. [12]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
13. [13]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
14. [14]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
15. [15]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
16. [16]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
17. [17]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
18. [18]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
19. [19]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(361)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142