Citation: CHEN Man-Sheng, DENG Yi-Fang, CUI Ying, LIU Dong-Cheng, LIANG Fu-Pei. Syntheses, Crystal Structures and Properties of 3D Heteronuclear Mn(Ⅱ)-Sm(Ⅱ) and 2D Homonuclear Sm(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1041-1048. doi: 10.11862/CJIC.2015.130 shu

Syntheses, Crystal Structures and Properties of 3D Heteronuclear Mn(Ⅱ)-Sm(Ⅱ) and 2D Homonuclear Sm(Ⅱ) Complexes

1.
1 School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, Guangxi 541004, China;
2.
2 Department of chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: CHEN Man-Sheng, LIANG Fu-Pei,
Received Date: 24 December 2014
Available Online: 30 January 2015
Fund Project: 国家自然科学基金(No.21461004,21271050) (No.21461004,21271050)中国博士后科学基金(No.2014M552534XB) (No.2014M552534XB)湖南省教育厅重点项目(No.14A021) (No.14A021)福建省教育厅A类重点(No.JA14261) (No.JA14261)功能金属有机材料湖南省普通高等学校重点实验室项目(No.13K06)资助和湖南省重点学科建设项目资助。 (No.13K06)

Two heteronuclear/homonuclear coordination polymers {[MnSm₂(INAIP)₄(H₂O)₄]·2H₂O}_n (1) and{[Sm(INAIP)(HINAIP)]·2H₂O}_n (2), where H₂INAIP=5-(isonicotinamido)isophthalic acid, were synthesized in a pot and their crystal structures were determined by X-ray diffraction analysis. Complex 1 crystallizes in the triclinic system, space group P1 with a=1.0188(5) nm, b=1.08386(6) nm, c=1.38721(8) nm, V=1.475(14) nm³, Z=1, D_c=1.802 g·cm^-3, μ=2.271 mm^-1, F(000)=793, R_int=0.0105, R₁=0.0512, wR₂=0.1319. Complex 2 is of monoclinic system, space group P2₁/c with a=1.34305(18) nm, b=1.3765(17) nm, c=1.62408(15) nm, V=2.7028(6) nm³, Z=4, D_c=1.861 g·cm^-3, μ=2.251 mm^-1, F(000)=1500, R_int=0.0514, R₁=0.0322, wR₂=0.0887. In complex 1, the 2D Sm-carboxylate layer is linked by Mn-Nand Mn-Ointeraction into complicated 3D framework. However, for complex 2, the central Sm(Ⅱ) atom is eight-coordinated by eight carboxylate oxygen atoms. The molecules are connected to form a 2D bilayer structure bridged by 5-(isonicotinamido)isophthalic acid. Furthermore, complex 1 shows adsorption behavior of CO₂ with almost no N₂ uptake, and the luminescent property of complexes 1 and 2 has also been investigated.
- heteronuclear complex;crystal structure;5-(isonicotinamido)isophthalic acid;hydrothermal synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142