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Citation: LIU Li-Hu, CHEN Shu-Lin, LIU Fan, XIANG Quan-Jun, FENG Xiong-Han, QIU Guo-Hong. Hydrothermal Preparation and Carbon Nanotube Modification of o-LiMnO2 Cathode Materials for Lithium Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 703-709. doi: 10.11862/CJIC.2015.100 shu

Hydrothermal Preparation and Carbon Nanotube Modification of o-LiMnO2 Cathode Materials for Lithium Battery

  • 1.

    College of Resources and Environment, Huazhong Agricultural University, Hubei Province, Wuhan, 430070, China

  • Corresponding author: QIU Guo-Hong, 
  • Received Date: 30 September 2014
    Available Online: 29 December 2014

    Fund Project: 国家自然科学基金(Nos.41171375、20807019) (Nos.41171375、20807019)教育部新世纪优秀人才支持计划(No.NCET-12-0862) (No.NCET-12-0862)霍英东教育基金会高等院校青年教师基金(No.141024) (No.141024)湖北省杰出青年人才基金(No. 2012FFA031) (No. 2012FFA031)中央高校基本科研业务费专项资金(Nos. 2013PY029、 2011PY030)。 (Nos. 2013PY029、 2011PY030)

  • Rechargeable lithium battery cathode materials orthorhombic LiMnO2(o-LiMnO2) was directly synthesized using hydrothermal reaction of MnCl2, LiOH, EDTA and NaClO solutions, and carbon nanotube modified o-LiMnO2(o-LiMnO2/CNTs composite) was further obtained by adding CNTs into the reaction system. The as-prepared samples were characterized by X-ray diffractometer and SEM/TEM, and their electrochemical performance was tested using constant current charge/discharge experiment and cyclic voltammetry. o-LiMnO2 was formed when hydrothermal reaction was performed at 180℃ for 24 h with LiOH/MnCl2 molar ratio as low as 8:1. o-LiMnO2 exhibited the initial discharge capacity of 76.0 mAh·g-1, and cycling capacity of 124.1 mAh·g-1 after 100 cycles. The formation of o-LiMnO2/CNTs composite decreased the particle size and electrochemical resistivity of single o-LiMnO2. The initial discharge capacity was 94.1 mAh·g-1, and increased and then kept stable after 45 cycles, and the cycling capacity was 159.8 mAh·g-1 after 100 cycles. This work facilitates the preparation and electrochemical performance improvement of o-LiMnO2 cathode materials for rechargeable lithium batteries.
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