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Citation: YANG Dai-Sheng, XU Li-Hua, CHEN Hui, ZHANG Li-Fang, NI Zhong-Hai, WANG Wen-Feng. Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged CrⅢ-CuⅡ Complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 565-570. doi: 10.11862/CJIC.2015.089 shu

Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged CrⅢ-CuⅡ Complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n

  • 1.

    1 School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China;

  • 2.

    2 School of Resources and Geosciences, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

  • Corresponding author: NI Zhong-Hai, 
  • Received Date: 18 September 2014
    Available Online: 10 January 2015

    Fund Project: 江苏省高校优势学科建设工程项目和中央高校基本科研业务费专项资金资助项目(No.2014ZDPY25)。 (No.2014ZDPY25)

  • A one-dimensional cyanide-bridged CrⅢ-CuⅡ complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n (cyclam=1, 4,8, 11-tetraazacyclotetradecane, bpb2-=1,2-bis(pyridine-2-carboxamido)-benzenate) (1) has been synthesized by the reaction of building blocks [Cu(cyclam)](ClO4)2 and K[Cr(bpb)(CN)2]. Single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in triclinic space group P1 with a=0.966 73(19) nm, b=1.345 1(3) nm, c= 1.382 0(3) nm, α=77.12(3)°, β=76.93(3)°, γ=82.02(3)°, V=1.699 1(6) nm3, Z=2, Dc=1.567 g·cm-3, μ=1.086 mm-1, F(000)=828, R1=0.041 3, wR2=0.120 0, the structure of complex 1 is a type of polymer with two different metal centers which are alternatively linked by cyanide group. Magnetic investigations indicate that complex 1 exhibits a weak ferromagnetic coupling between CrⅢ and CuⅡ centers through the cyanide bridge.
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    1. [1]

      [1] Gatteschi D, Sessoli R. Angew. Chem., 2003,115:278-309

    2. [2]

      [2] Tang J K, Si S F, Wang L Y, et al. Inorg. Chem. Commun., 2002,5:1012-1015

    3. [3]

      [3] Ni Z H, Kou H Z, Zhang L F, et al. Angew. Chem. Int. Ed., 2005,44:7742-7745

    4. [4]

      [4] Caneschi A, Gatteschi D, Renard J P, et al. Inorg. Chem., 1989,28:1976-1980

    5. [5]

      [5] Brechin E K, Boskovic C, Wernsdorfer W, et al. J. Am. Chem. Soc., 2002,33:9710-9711

    6. [6]

      [6] Gianneschi N C, Masar M S, Mirkin C A. Acc. Chem. Res., 2005,38:825-837

    7. [7]

      [7] Tabares L C, Navarro J A R, Salas J M. J. Am. Chem. Soc., 2001,123:383-387

    8. [8]

      [8] Zhang K L, Chen W, Xu Y, et al. Polyhedron, 2001,20:2033-2036

    9. [9]

      [9] Mironov V S, Chibotaru L F, Ceulemans A J. J. Am. Chem. Soc., 2003,125:9750-9760

    10. [10]

      [10] Visinescu D, Toma L M, Lloret F, et al. Dalton Trans., 2008,31:4103-4105

    11. [11]

      [11] Berlinguette C P. Angew. Chem., 2003,42:1523-1526

    12. [12]

      [12] Shen W Z, Chen X Y, Cheng P, et al. Z. Anorg. Allg. Chem., 2003,629:591-594

    13. [13]

      [13] Luo J, Hong M, Weng J, et al. Inorg. Chim. Acta, 2002, 329:59-65

    14. [14]

      [14] Kou H Z, Liao D Z, Jiang Z H. Inorg. Chem. Commun., 2000, 3:151-154

    15. [15]

      [15] Mehrotra R C, Singh A, Sogani S. Chem. Soc. Rev., 1994, 23:215-225

    16. [16]

      [16] Shi Z L, Lin N. Chem. Phys., 2010,11:97-107

    17. [17]

      [17] Mock M T, Kieber M T, Popescu C V, et al. Inorg. Chim. Acta, 2009,362:4553-4562

    18. [18]

      [18] Zhang D P, Zhang L F, Zhao Z D, et al. Inorg. Chim. Acta, 2011,377:165-169

    19. [19]

      [19] Li G L, Ni Z H, Cheng W Q, et al. Inorg. Chem. Commun., 2013,31:58-61

    20. [20]

      [20] Liu C M, Zhang D Q, Zhu D B. Inorg. Chem., 2009,48: 4980-4987

    21. [21]

      [21] Hu X, Zeng Y F, Chen Z, et al. Cryst. Growth Des., 2009,9: 421-426

    22. [22]

      [22] Stamatatos T C, Dionyssopoulou S, Efthymiou G, et al. Inorg. Chem., 2005,44:3374-3376

    23. [23]

      [23] Lan Y Q, Li S L, Fu Y M, et al. Dalton Trans., 2008,31: 6796-6807

    24. [24]

      [24] Ni Z H, Kou H Z, Zhao Y H, et al. Inorg. Chem., 2005,44: 2050-2059

    25. [25]

      [25] MIAO Bao-Xi(苗宝喜), LI Guo-Lin(李国玲), ZHAO Yun (赵云), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(11):2470-2474

    26. [26]

      [26] Li G L, Nie J, Chen H, et al. Inorg. Chem. Commun., 2012, 19:66-69

    27. [27]

      [27] Kolinski R A, Korybut-Daszkiewicz B. Inorg. Chim. Acta, 1975,14:237-245

    28. [28]

      [28] Chen H, Miao B X, Ni Z H, et al. Inorg. Chim. Acta, 2013,404:34-40

    29. [29]

      [29] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122

    30. [30]

      [30] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structure, University of Göttingen, Germany, 1997.

    31. [31]

      [31] Borrás-Almenar J J, Clemente-Juan J M, Coronado E, et al. Inorg. Chem., 1999,38:6081-6088

    32. [32]

      [32] Borrás-Almenar J J, Clemente-Juan J M, Coronado E, et al. J. Comput. Chem., 2001,22:985-991

    33. [33]

      [33] Zhang D P, Wang H L, Ni Z H, et al. Inorg. Chem., 2009,48:5488-5496

    34. [34]

      [34] Bieńko A, Suracka K, Mroziński J, et al. Polyhedron, 2010, 12:2546-2552

    35. [35]

      [35] Parker R J, Lu K D, Batten S R, et al. J. Chem. Soc. Dalton Trans., 2002,19:3723-3730

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