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水分子对金属有机骨架材料结构及性能的影响

张倬铭 ,  杨江峰 ,  王勇 ,  李晋平

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引用本文: 张倬铭, 杨江峰, 王勇, 李晋平. 水分子对金属有机骨架材料结构及性能的影响[J]. 无机化学学报, 2015, (4): 627-634. doi: 10.11862/CJIC.2015.075 shu
Citation:  ZHANG Zhuo-Ming, YANG Jiang-Feng, WANG Yong, LI Jin-Ping. Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks[J]. Chinese Journal of Inorganic Chemistry, 2015, (4): 627-634. doi: 10.11862/CJIC.2015.075 shu

水分子对金属有机骨架材料结构及性能的影响

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    太原理工大学精细化工研究所, 太原 030024

    • 通讯作者: 李晋平 jpli211@hotmail.com
  • 基金项目:

    国家自然科学基金项目(No.21136007、51302184) (No.21136007、51302184)

    973前期专项(2014CB260402)项目资助。 (2014CB260402)

摘要: 金属有机骨架材料(Metal-Organic Frameworks, MOFs)是一种新型有机-无机杂化材料,其在气体的吸附分离、催化、磁学、生物医学等领域表现出诱人的应用前景。但是,在水分子存在的情况下MOFs结构及性能会受到很大的影响,极大的阻碍了其工业化进程。本文系统介绍了水分子对MOFs结构的破坏机理,并从金属和配体两方面总结了在水分子存在的情况下MOFs的稳定性问题;阐述了水分子的吸附机理以及吸附水分子后MOFs性能的变化;并且对水分子影响问题的研究趋势做了展望,以期为今后的研究提供参考。

English

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  • 收稿日期:  2014-10-14
  • 网络出版日期:  2014-12-25
通讯作者: 陈斌, bchen63@163.com
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