Citation: JI Ke-Ming, MENG Fan-Hui, GAO Yuan, LI Zhong. Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 267-274. doi: 10.11862/CJIC.2015.050 shu

Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Zhong,
Received Date: 4 August 2014
Available Online: 7 November 2014
Fund Project: 国家"973"计划(No.2012CB723105) (No.2012CB723105)山西省青年基金(No.2013021007-4) (No.2013021007-4)中国博士后科学基金(2013M541210) (2013M541210)太原理工大学校青年团队基金(No.2013T091)资助项目 (No.2013T091)

Ni-Al₂O₃, Ni-ZrO₂, Ni-La₂O₃ and Ni-CeO₂ catalysts were prepared by solution combustion method using Al(NO₃)₃, ZrO(NO₃)₂, La(NO₃)₃ and Ce(NO₃)₃ (mixed with Ni(NO₃)₂ and urea in aqueous solution) as the support precursor, respectively. The COmethanation performances of catalysts were studied in slurry-bed reactor, and the catalysts were characterized by low temperature N₂ adsorption-desorption, XRD, SEM, TEM, H₂-TPRand H₂ chemsorption. The results show that the combustion preparation process of Ni-Al₂O₃ catalyst using Al(NO₃)₂ as the precursor is stable for long-duration(up to 23 s) and the catalyst has larger surface area (468 m²·g^-1) and metal surface area (10 m²·g^-1), smaller Ni particle (3~5 nm), excellent dispersion of Ni, and the catalyst has good catalytic performance, whose COconversion and CH₄ selectivity are 94% and 95%, respectively, and no catalyst deactivation is observed in 100h. The preparation process for catalysts using ZrO(NO₃)₂ and La(NO₃)₃ as precursors does not show obvious flame and burning time is also shorter (12 s and 5 s), the surface areas, metal surface areas and catalytic performances are lower than that of Ni-Al₂O₃ while that for the catalyst using Ce(NO₃)₂ as the precursor has high intensity combustion. The catalyst obtained from Ce(NO₃)₂ precursor shows lower surface area (22 m²·g^-1) and metal surface area (5 m²·g^-1), larger Ni particle and worse dispersion of Ni and the worst methanation catalytic performance with COconversion and CH₄ selectivity of 41% and 89%, respectively.
- catalysis;catalyst prepration;slurry-bed reactor;CO methanantion;solution combustion method;Ni-based catalyst;support
1. [1]
  [1] Kopyscinski J, Schildhauer T J, Biollaz S M A. Fuel, 2010,89 (8):1763-1783
2. [2]
  [2] Zhang J, Bai Y, Zhang Q, et al. Fuel, 2014,132:211-218
3. [3]
  [3] Gao J, Wang Y, Ping Y, et al. RSC Adv., 2012,2(6):2358-2368
4. [4]
  [4] CUI Xiao-Xi(崔晓曦), FAN Hui(范辉), ZHENG Hua-Yan(郑华艳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(3):495-502
5. [5]
  [5] CUI Xiao-Xi(崔晓曦), MENG Fan-Hui(孟凡会), HE Zhong (何忠), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 30(2):277-283
6. [6]
  [6] Zhao A, Ying W, Zhang H, et al. Catal. Comun., 2012,17: 34-38
7. [7]
  [7] Tada S, Shimizu T, Kameyama H, et al. Int. J. Hydrogen Energy, 2012,37(7):5527-5531
8. [8]
  [8] Cai M, Wen J, Chu W, et al. J. Nat. Gas Chem., 2011,20 (3):318-324
9. [9]
  [9] SONG Huan-Ling(宋焕玲), YANG Jian(杨建), ZHAO Jun(赵军), et al. Chin. J. Catal.(催化学报), 2010,31(1):21-23
10. [10]
  [10] Meng F H, Zhong P Z, Li Z, et al. J. Chem, 2014,2014:1-7
11. [11]
  [11] MENG Fan-Hui(孟凡会), LIU Jun(刘军), LI Zhong(李忠), et al. J. Fuel Chem. Technol.(燃料化学学报), 2014,42(2): 231-237
12. [12]
  [12] Pfeil T L, Pourpoint T L, Groven L J. Int. J. Hydrogen Energy, 2014,39(5):2149-2159
13. [13]
  [13] Dinka P, Mukasyan A S. J. Phys. Chem. B, 2005,109(46): 21627-21633
14. [14]
  [14] Sharma S, Hu Z, Zhang P, et al. J. Catal., 2011,278(2):297-309
15. [15]
  [15] Colussi S, Gayen A, Llorca J, et al. Ind. Eng. Chem. Res., 2012,51(22):7510-7517
16. [16]
  [16] González-Cortés S L, Imbert F E. Appl. Catal. A, 2013,452: 117-131
17. [17]
  [17] Jung C H, Jalota S, Bhaduri S B. Mater. Lett., 2005,59(19/20):2426-2432
18. [18]
  [18] LU Chang(路长), ZHOU Jian-Jun(周建军), LIN Qi-Zhao(林其钊), et al. J. Combust. Sci. Technol.(燃烧科学与技术), 2005,11(1):41-46
19. [19]
  [19] WU Shu-Rong(吴淑荣), XIONG Wei-Miao(熊为淼), HE Ming-An(何明安), et al. J. Northwest Univ.(西北大学学报), 1981,22(3):32-38
20. [20]
  [20] Zou X, Wang X, Li L, et al. Int. J. Hydrogen Energy, 2010, 35(22):12191-12200
21. [21]
  [21] Yang J, Wang X, Li L, et al. Appl. Catal. B, 2010,96(1-2): 232-237
22. [22]
  [22] Koo K Y, Roh H-S, Seo Y T, et al. Int. J. Hydrogen Energy, 2008,33(8):2036-2043
23. [23]
  [23] Zhang J, Xu H, Jin X, et al. Appl. Catal. A, 2005,290(1-2): 87-96
24. [24]
  [24] Nagai M, Zahidul A M, Kunisaki Y, et al. Appl. Catal. A, 2010,383(1-2):58-65
25. [25]
  [25] Kam R, Selomulya C, Amal R, et al. J. Catal., 2010,273(1): 73-81
26. [26]
  [26] LIU Na(刘娜), DU Xia-Ru(杜霞茹), YUAN Zhong-Shan(袁中山), et al. J. Chinese Soc. Rare Earths(中国稀土学报), 2005,23(1):26-30
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
3. [3]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
4. [4]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
5. [5]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
8. [8]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
11. [11]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
12. [12]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
13. [13]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
14. [14]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
15. [15]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
18. [18]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(171)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142