Citation: HUANG Deng-Deng, CHEN Li-Zhuang. Assembly of Two Coordination Polymers Based on Tetrazole Derivatives[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 377-384. doi: 10.11862/CJIC.2015.047 shu

Assembly of Two Coordination Polymers Based on Tetrazole Derivatives

HUANG Deng-Deng ,
CHEN Li-Zhuang ^,

1.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: CHEN Li-Zhuang,
Received Date: 6 September 2014
Available Online: 13 November 2014
Fund Project: 国家自然科学基金(No.21201087) (No.21201087)江苏省自然科学基金(No.BK20131244) (No.BK20131244)江苏省教育厅基金(No.11KJB150004)资助项目 (No.11KJB150004)江苏省高校研究生实践创新计划项目(No.SJZZ_0142)资助项目 (No.SJZZ_0142)

Two mixed metal-organic coordination polymers, namely {[Zn(4-PTZ)₂Cl₂]·4H₂O}_n (1) and {[Cd₃(4-PTZ)₂(H₂O)₂Cl₆]·3H₂O}_n (2), were synthesized under hydrothermal condition using5-(4-pyridyl)tetrazolate (4-PTZ), which exhibited diverse coordination modes in two complexes. The two compounds are both crystallized in a monoclinic system. Compound 1: a=0.69175(8) nm; b=2.6688(3) nm; c=1.12266(12) nm; β=93.5350(10)°; V=2.0687(4) nm³; Z=4; R₁=0.0318 for I>2σ(I); wR₂=0.0829; space group P2₁/n. Compound 2: a=1.89713(13) nm; b=1.05579(7) nm; c=1.44649(10) nm; β=102.4890(10)°; V=2.8287(3) nm³; Z=4; R₁=0.0262 for I>2σ(I); wR₂=0.1343; space group C2/c. They are characterized by elemental analysis, IRspectroscopy and TGA. In addition, 1 and 2 have ultraviolet fluorescence emissions in the solid state at room temperature. CCDC: 984430, 1; 984429, 2.
- coordination polymer;1D chain;hydrothermal reaction;tetrazole;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Assembly of Two Coordination Polymers Based on Tetrazole Derivatives

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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