Citation: PENG Jiao-Yu, LIN Feng, YANG Bo, WANG Li-Ping, Dinnebier E.Robertc, DONG Ya-Ping, LI Wu. Synthesis, Structure and Properties of a Magnesium Borate in Concentrated Boron-Bearing Salt Lake Brine by Dilution Method[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 305-312. doi: 10.11862/CJIC.2015.042 shu

Synthesis, Structure and Properties of a Magnesium Borate in Concentrated Boron-Bearing Salt Lake Brine by Dilution Method

PENG Jiao-Yu ^1,2,3 ,
LIN Feng ^1,2,3 ,
YANG Bo ¹ ,
WANG Li-Ping ^1,2,3 ,
Dinnebier E.Robertc ⁴ ,
DONG Ya-Ping ^1,2,*,, ,
LI Wu ¹

1.
Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resource, Chinese Academy of Science, Xining 810008, China
4.
Max-Planck Institute for Solid State Research, Stuttgart 70569, Germany

Corresponding author: DONG Ya-Ping, Dongyaping@hotmail.com
Received Date: 13 July 2015
Revised Date: 21 October 2015

Figures(8)

A new magnesium borate mineral, Mg[B₆O₇(OH)₆]·5H₂O was synthesized via dilution method from boron-bearing Na-K-Mg-Cl-SO₄ salt lakes. The crystal structure of the new phase was solved and refined using X-ray powder diffraction data and characterized with FTIR and Raman. Its asymmetric unit consists of one Mg atom, one B₆O₇(OH)₆ cluster and five H₂O molecules. The Mg atom is 6-coordinated with six O atoms to form a MgO₆ octahedron. Thermal gravimetry (TG/DSC) was used to investigate the thermal behavior of the new compound. During the high temperature decomposition process the dehydrated product MgB₄O₇ formed. The optical absorption characteristic of this new mineral was investigated by UV-Vis spectrometer and its energy gap E_g is about 4.44 eV.
- magnesium borate,
- boron-bearing salt lake,
- dilution method,
- structure,
- thermal behavior
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沈阳化工大学材料科学与工程学院沈阳 110142