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Citation: LI Guo-Feng, WANG Ya-Nan, WANG Qing-Wei, LI Xiu-Mei, JI Jian-Ye, PAN Ya-Ru. Syntheses and Crystal Structures of Two Complexes of Manganese, Cobalt Assembled by5-Nitroisophthalic Acid and Bis(imidazol) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 183-190. doi: 10.11862/CJIC.2015.034 shu

Syntheses and Crystal Structures of Two Complexes of Manganese, Cobalt Assembled by5-Nitroisophthalic Acid and Bis(imidazol) Ligands

  • 1.

    1. Department of Assets Management, Jilin Normal University, Siping, Jilin 136000, China;

  • 2.

    2. Key Laboratory of Preparation and Applications of Environmental Friendly Materials of Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

  • 3.

    3 Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China

  • Corresponding author: WANG Qing-Wei,  LI Xiu-Mei, 
  • Received Date: 4 July 2014
    Available Online: 30 August 2014

    Fund Project: 吉林省教育厅科学技术研究(吉教科合字[2013]第384号) (吉教科合字[2013]第384号)吉林省科技发展计划(No.201205080)资助项目. (No.201205080)

  • Two new complex [Mn(NIPH)(mbix)]n (1) and [Co(NIPH)(mbix)(H2O)3]2n·2nH2O (2) (H2NIPH=5-nitroiso-phthalic acid, mbix=1,3-bis(imidazol-1-ylmethyl)benzene) have been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectrum, UVspectrum, TGand single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions. CCDC: 979616, 1; 1011701, 2.
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