Citation: DENG Bing-Xin, ZHANG Bo, JIANG Jian-Feng. Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 153-158. doi: 10.11862/CJIC.2015.014 shu

Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction

1.
Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: ZHANG Bo,
Received Date: 5 July 2014
Available Online: 13 October 2014

5%ZrO₂/MCM-41 and 5%ZrO₂-5%M₂O₃/MCM-41(M=La,Ce,Sm,Gd)were prepared by the impregnation method. The hydrogen transfer reduction of acetophenone with 2-propanol was investigated over these catalysts. The catalysts were characterized with XRD, N₂ adsorption-desorption and FTIR spectra of adsorbed pyridine. The results show that ZrO₂ and rare-earth metal oxides disperse on the surface of MCM-41 supports in an amorphous phase or as tiny crystal particles lower than the detection limit of XRD. The catalytic activity obviously varies upon loading rare-earth metal oxides on₅%ZrO₂-MCM-41, The activities of the catalysts decrease in the order of 5%ZrO₂-5%La₂O₃/MCM-41 > 5%ZrO₂-5%Sm₂O₃/MCM-41 > 5%ZrO₂-5%Gd₂O₃/MCM-41 > 5%ZrO₂/MCM-41 > 5%ZrO₂-5%Ce₂O₃/MCM-41. Addition of rare-earth metal oxides leads to strengthening the acidity of Zr-OH, Lewis acid sites and Brönsted acid sites on the catalyst surface. On the other hand, the addition of La₂O₃ can obviously enhance the number of acid sites on the catalyst surface. On the contrary, the loading of Sm₂O₃、Gd₂O₃ results in the slight decrease in the number of acid sites on the catalyst surface, especially, the addition of Ce₂O₃ leads to a significant drop in the number of acid sites.
- zirconia;MCM-41 mesoporous molecular sieve;rare-earth metal oxides;acetophenone;hydrogen transfer reaction
1. [1]
  [1] Arai M, Takahashi H, Shirai M, et al. Appl. Catal. A, 1999, 176:229-236
2. [2]
  [2] Sudhindra N M , Ram S S, Minaz A G, et al. J. Colloid Interface Sci., 2005,281(1):164-170
3. [3]
  [3] Uysal B, Buyuktas B S. Arkivoc, 2007,14:134-140
4. [4]
  [4] Corma A, Domine M E, Nemeth L, et al. J. Am. Chem. Soc., 2002.124(13):3194-3195
5. [5]
  [5] Akata B, Warzywoda J, Albert S J. J. Catal., 2004.222(2): 397-403
6. [6]
  [6] Zhu Y Z, Liu S H, Janenicke S. J. Catal., 2004,227(1):1- 10
7. [7]
  [7] LIU Jian-Hong(刘建红), XIA Feng(夏峰), FAN Bin-Bin (范彬彬), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(6):980-985
8. [8]
  [8] Samuel P P, Shylesh S, Singh A P. J. Mol. Catal. A: Chem., 2007,266(1/2):11-20
9. [9]
  [9] JIN Bin(金滨), ZHANG Bo(张波), LI Xiu-Juan(李秀娟), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2008, 22(2):270-276
10. [10]
  [10] ZHANG Bo(张波), TANG Min-Hui(汤明慧), YUAN Jian (袁剑), et al. Chin. J. Catal.(催化学报), 2012,33:914-922
11. [11]
  [11] Zhu Y Z, Liu S H, Jaenicke S, et al. Catal. Today, 2004,97 (4):249-255
12. [12]
  [12] XU Chun-Lei(徐春雷), ZHANG Bo(张波) ,YUAN Jian (袁剑), et al. Acta Chim. Sinica(化学学报), 2011,69(4):368 -374
13. [13]
  [13] Aramendia M A, Borau V, Jimenez C, et al. J. Catal., 1999, 183(1):119-127
14. [14]
  [14] YUAN Jian(袁剑), ZHANG Bo(张波), TANG Ming-Hui (汤明慧), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2013,27(5):818-824
15. [15]
  [15] YUAN Jian(袁剑), ZHANG Bo(张波), TANG Ming-Hui (汤明慧), et al. Chem. J. Chinese Universities(高等学校化学学报), 2012,33(6):1326-1332
16. [16]
  [16] ZHANG Bo(张波), SHEN Lian(慎炼), ZHOU Chun-Hui (周春晖), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2001,15(1):29-35
17. [17]
  [17] Rana S, Mallick S, Rath D, et al. J. Chem. Sci., 2012,124 (5):1117-1125
18. [18]
  [18] Gregori M, Benito P, Fornasari G, et al. Microporous Mesoporous Mater., 2014,190:1-9
19. [19]
  [19] Saraiva M S, Fernandes C I, Nunes T G, et al. J. Organomet. Chem., 2014,751:443-452
20. [20]
  [20] Mekhemer G A H. Phys. Chem. Chem. Phys., 2002,4:5400 -5405
21. [21]
  [21] Damyanova S, Petrov L, Centeno M A, et al. Appl. Catal. A: Gen., 2002,224(1/2):271-284
22. [22]
  [22] Zhang B, Shi N F, Xu C L, et al. J. Fluorine Chem., 2010, 131(5):554-560
23. [23]
  [23] Marques J P, Gener I, Ayrault P, et al. Microporous Mesoporous Mater., 2003,60:251-262
24. [24]
  [24] Martins A, Silva J M, Henriques C, et al. Catal. Today, 2005,107-108:663-670
25. [25]
  [25] Chuah G K, Jaenicke S, Zhu Y Z, et al. Curr. Org. Chem., 2006,10(13):1639-1654
26. [26]
  [26] Zhu Y Z, Jaenicke S, Chuah G K. J. Catal., 2003,218(2):396 -404
27. [27]
  [27] Warner B P, D'Alessio J A, Morgan A N, et al. Inorg. Chim. Acta, 2000,309(1):45-48
28. [28]
  [28] Axpuac S, Aramendøa M A, Carrillo J H, et al. Catal. Today, 2012,187(1):183-190
29. [29]
  [29] Urbano F J, Aramendia M A, Marinas A, et al. J. Catal., 2009,268(1):79-88
1. [1]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
2. [2]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
3. [3]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
4. [4]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
7. [7]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
8. [8]
  Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
9. [9]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
10. [10]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
13. [13]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
14. [14]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
15. [15]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
16. [16]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
17. [17]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
18. [18]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
19. [19]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
20. [20]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(351)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Rare Earth Element in ZrO2-M2O3/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction