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Citation: SHI Pei, SHEN Wei, YU Yu-Ye, WU Xiao-Yong, ZHAO Guo-Liang. A Series of Zinc Polymer with 3D Construction: Syntheses, Structures and DNA-Binding[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 45-53. doi: 10.11862/CJIC.2015.012 shu

A Series of Zinc Polymer with 3D Construction: Syntheses, Structures and DNA-Binding

  • 1.

    1. College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China;

  • 2.

    2. Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China;

  • 3.

    3. Jinhua Polytechnic, Jinhua, Zhejiang 321004, China

  • Corresponding author: ZHAO Guo-Liang, 
  • Received Date: 7 May 2014
    Available Online: 9 September 2014

    Fund Project: 浙江省自然科学基金(No.LY12B01003)资助项目 (No.LY12B01003)

  • Three zinc complexes [Zn(bptc)0.5]n (1), [Zn2(bptc)(H2O)3]n·nH2O (2), [Zn2(bptc)(H2O)(bipy)1.5]n·nH2O (3), were synthesized under hydrothermal reactions by using biphenyl-2,4,4',6-tetracarboxylic acid (H4bptc) and 4,4'-Bipyridine (bipy). They were characterized by elemental analysis, IR spectra. Crystal structures of the complexes were determined by single crystal X-ray diffraction method. Complex 1 is binuclear structure, eight ring metal clusters with (4,4) topology. Complex 2 is a (4,5,6) topology construction. Complex 3 is a 3D network structure formed by ligand and auxiliary ligand. The interaction between three complexes and DNA were studied by EtBr fluorescence probe. Add the rigid auxiliary ligand, the interaction of complex 3 to the DNA is stronger than complex 1 and 2. CCDC: 952957, 1; 952958, 2; 952959, 3.
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