Citation: HUANG Yan-Ping, ZHANG Xiao, LIU Lei, ZHANG Nan-Xi, XU Xian-Zhu. Synthesis and Crystal Structure of Transition Metal Coordination Compounds with Triethylenediamine Ligand and Their Florescence Properties Studies[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1001-1008. doi: 10.11862/CJIC.2014.186 shu

Synthesis and Crystal Structure of Transition Metal Coordination Compounds with Triethylenediamine Ligand and Their Florescence Properties Studies

1.
1 State Key Laboratory of Urban Water Resource and Environment;

Received Date: 8 April 2013
Available Online: 8 March 2014
Fund Project: 国家自然科学基金青年基金(No.51108122)；哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金项目(No.QA201025)；中央高校基本科研业务费专项资金(No.HIT.NSRIF.2010053)以及哈尔滨市科技创新人才研究专项资金项目(青年科技创新人才)(No.2010RFQXG035) (No.51108122)；哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金项目(No.QA201025)；中央高校基本科研业务费专项资金(No.HIT.NSRIF.2010053)以及哈尔滨市科技创新人才研究专项资金项目(青年科技创新人才)(No.2010RFQXG035)哈尔滨市科技创新人才研究专项资金项目(优秀学科带头人)(No.2007RFXXG018)共同资助。 (优秀学科带头人)(No.2007RFXXG018)

Aseries of transition metal coordination compounds based on the ligand, triethylenediamine(dabco), [CdCl₃H(dabco)₂] (1), [CoCl₃Hdabco] (2), [NiCl₂(H₂O)₃Hdabco]Cl (3), [CuCl₃H(dabco)₂]Cl·H₂O (4) have been prepared and characterized by elemental analyses, IRspectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence.
- transition-metal coordination compounds;triethylenediamine;crystal structure;florescence properties
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沈阳化工大学材料科学与工程学院沈阳 110142