Citation: DONG Li-Jun, LIU Yao, JI Xue-Mei, WEI Ya-Bo, XU Qing-Hong. Effect of Metal Ion on Conversion from M²⁺/Fe²⁺/Fe³⁺/LDHs to Spinel Ferrites under Mild Conditions[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1119-1127. doi: 10.11862/CJIC.2014.172 shu

Effect of Metal Ion on Conversion from M²⁺/Fe²⁺/Fe³⁺/LDHs to Spinel Ferrites under Mild Conditions

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 15 BeiSanhuan East Road, ChaoYang District, Beijing 100029, China

Received Date: 31 October 2013
Available Online: 17 January 2014
Fund Project: 国家自然科学基金(No.U1362113)；教育部科技创新基金的支持(No.pt2012112)资助项目。 (No.U1362113)；教育部科技创新基金的支持(No.pt2012112)

The Effect of divalent metal ion was studied on conversion of M²⁺/Fe²⁺/Fe³⁺-LDHs (M=Co, Ni, Mn, Zn) to spinel ferrites under mild conditions (below 100 ℃ in open air). The results show that the conversion is not only affected by aging temperature but also by position of M²⁺ in periodic table of elements. Large radius of M²⁺ ions will result in much easier formation of spinel ferrites from LDH microcrystallines when these ions are in the same period and close to each other. Also the existence of Fe²⁺ plays an important role in the process, and the conversion could not happen without participation of Fe²⁺ under the conditions studied.
- spinel ferrite;LDH microcrystalline;conversion;elemental effects;mild conditions
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Metal Ion on Conversion from M2+/Fe2+/Fe3+/LDHs to Spinel Ferrites under Mild Conditions

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通讯作者: 陈斌, bchen63@163.com

Effect of Metal Ion on Conversion from M²⁺/Fe²⁺/Fe³⁺/LDHs to Spinel Ferrites under Mild Conditions