Citation: YUAN Hou-Qun, HU Chun-Yan, BAO Guang-Ming, XIAO Wei, SUN Ting-Ting, XING Yong-Heng. Synthesis, Crystal Structures of Cyclic Dinuclear Zn(Ⅱ) and Cd(Ⅱ) Complexes with 3-Nitrophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1195-1200. doi: 10.11862/CJIC.2014.166 shu

Synthesis, Crystal Structures of Cyclic Dinuclear Zn(Ⅱ) and Cd(Ⅱ) Complexes with 3-Nitrophthalic Acid

1.
1 School of Science, Jiangxi Agricultural University, Nanchang 330045, China;

Received Date: 7 October 2013
Available Online: 18 December 2013
Fund Project: 江西省自然科学(青年)基金(No.20132BAB213002)；江西省科技支撑项目(No.20112BBF60023)；人事部留学人员科技活动项目择优资助(启动类)；教育部高校博士点专项基金(No.20113603120006)；江西省教育厅基金(No.GJJ12252，No.GJJ12254)资助项目。 (青年)基金(No.20132BAB213002)；江西省科技支撑项目(No.20112BBF60023)；人事部留学人员科技活动项目择优资助(启动类)；教育部高校博士点专项基金(No.20113603120006)；江西省教育厅基金(No.GJJ12252，No.GJJ12254)

Two complexes [Zn₂(npa)₂(Im)₄] (1) and [Cd₂(npa)₂(2,2'-bipy)₂(H₂O)₂]·2H₂O (2) (H₂npa=3-nitrophthalic acid, Im=imidazole, 2,2'-bipy=2,2'-bipyridine) were constructed by the use of 3-nitrophthalic acid and imidazole or 2,2'-bipyridine, respectively. The complexes were characterized by elemental analysis, IR, and the crystal structures were determined by single X-ray diffraction. The thermal stabilities of the complexes were studied by thermal gravimetric analysis. The two complexes are dinuclear structures, and both contain M₂C₈O₄ 14-membered rings. The dinuclear units extend to 3D network through intermolecular hydrogen bonding interactions for complex 1, while a 2D sheet structure is formed for complex 2 by hydrogen bonding and π-π stacking interactions.
- 3-nitrophthalic acid;imidazole;2,2’-bipyridine;Zn²⁺;Cd²⁺;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142