Citation: YUAN Hou-Qun, HU Chun-Yan, BAO Guang-Ming, XIAO Wei, SUN Ting-Ting, XING Yong-Heng. Synthesis, Crystal Structures of Cyclic Dinuclear Zn(Ⅱ) and Cd(Ⅱ) Complexes with 3-Nitrophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1195-1200. doi: 10.11862/CJIC.2014.166 shu

Synthesis, Crystal Structures of Cyclic Dinuclear Zn(Ⅱ) and Cd(Ⅱ) Complexes with 3-Nitrophthalic Acid

1.
1 School of Science, Jiangxi Agricultural University, Nanchang 330045, China;

Received Date: 7 October 2013
Available Online: 18 December 2013
Fund Project: 江西省自然科学(青年)基金(No.20132BAB213002)；江西省科技支撑项目(No.20112BBF60023)；人事部留学人员科技活动项目择优资助(启动类)；教育部高校博士点专项基金(No.20113603120006)；江西省教育厅基金(No.GJJ12252，No.GJJ12254)资助项目。 (青年)基金(No.20132BAB213002)；江西省科技支撑项目(No.20112BBF60023)；人事部留学人员科技活动项目择优资助(启动类)；教育部高校博士点专项基金(No.20113603120006)；江西省教育厅基金(No.GJJ12252，No.GJJ12254)

Two complexes [Zn₂(npa)₂(Im)₄] (1) and [Cd₂(npa)₂(2,2'-bipy)₂(H₂O)₂]·2H₂O (2) (H₂npa=3-nitrophthalic acid, Im=imidazole, 2,2'-bipy=2,2'-bipyridine) were constructed by the use of 3-nitrophthalic acid and imidazole or 2,2'-bipyridine, respectively. The complexes were characterized by elemental analysis, IR, and the crystal structures were determined by single X-ray diffraction. The thermal stabilities of the complexes were studied by thermal gravimetric analysis. The two complexes are dinuclear structures, and both contain M₂C₈O₄ 14-membered rings. The dinuclear units extend to 3D network through intermolecular hydrogen bonding interactions for complex 1, while a 2D sheet structure is formed for complex 2 by hydrogen bonding and π-π stacking interactions.
- 3-nitrophthalic acid;imidazole;2,2’-bipyridine;Zn²⁺;Cd²⁺;crystal structure
1. [1]
  [1] Cook T R, Zheng Y R, Stang P J. Chem. Rev., 2013, 113: 734-777
2. [2]
  [2] Pradeep C P, Das S K. Coord. Chem. Rev., 2013, 257:1699-1715
3. [3]
  [3] Lehn J M. Top Curr. Chem., 2012, 322:1-32
4. [4]
  [4] Alexeev Y E, Kharisov B I, García T C H, et al. Coord. Chem. Rev., 2010, 254:794-831
5. [5]
  [5] Shen X Q, Qiao H B, Li Z J, et al. Inorg. Chem. Acta, 2006, 359:642-648
6. [6]
  [6] LI Feng-Ge(李烽格), ZHANG Qing-Juan(张庆娟), DING Yan-Feng(丁彦峰), et al. Proceedings of 14th Chinese Cyclic Chemistry and 6th Supramolecular Chemistry Conference(全国第十四届大环化学暨第六届超分子化学学术研讨会论文专辑). Lanzhou:[s.n.] , 2008:416-418
7. [7]
  [7] Deng Y H, Liu J, Wu B, et al. Eur. J. Inorg. Chem., 2008: 1712-1718
8. [8]
  [8] Song Y S, Yan B, Chen Z X. Appl. Organometal. Chem., 2007, 21:150-155
9. [9]
  [9] NI Ying-Rui(倪迎瑞), GAO Ling-Xiang(高玲香), LIU Ying-Hua(刘迎花), et al. Journal of Shaanxi Normal University: Nat. Sci.(陕西师范大学学报:自然科学版), 2009, 37(4):60-63
10. [10]
  [10] JIANG Xiu-Rong(姜秀榕), WEN De-Cai(温德才), DONG Yan(董雁), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(2):393-396
11. [11]
  [11] Nowicka B, Korzeniak T, Stefańczyk O, et al. Coord. Chem. Rev., 2012, 256:1946-1971
12. [12]
  [12] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼). Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(12):2650-2654
13. [13]
  [13] WEI Tai-Bao(魏太保), ZHANG Qin-Sheng(张勤生), CAO Cheng(曹成), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(7):1291-1294
14. [14]
  [14] ZHANG You-Ming(张有明), ZHANG Qin-Sheng(张勤生), LIN Qi(林奇), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011, 32(9):2181-2186
15. [15]
  [15] LIU Jian-Feng(刘建锋), LIU Yan(刘艳), LÜ Xu-Yan(吕旭燕), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29 (1):155-159
16. [16]
  [16] SHI Zhi-Qiang(石智强), JI Ning-Ning(季宁宁), HE Guo-Fang(何国芳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(6):1279-1285
17. [17]
  [17] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.
18. [18]
  [18] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.
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沈阳化工大学材料科学与工程学院沈阳 110142