Citation: XU Jin-Fang, SHI Wei, NI Zhe-Ming, SUN Zhi-Yin, QIAN Ping-Ping. Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 977-983. doi: 10.11862/CJIC.2014.144 shu

Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides

1.
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China

Received Date: 15 November 2013
Available Online: 8 January 2014
Fund Project: 国家自然科学基金资助项目(No.)。 (No.)

The surface modification of magnesium-aluminum hydrotalcites was made by sodium dodecyl benzene sulfonate (SDBS), Tween-80 and anionic-nonionic surfactant. Inverse gas chromatography (IGC) was used to investigate the surface properties of the MgAl-LDHs, SDBS-LDHs, Tween-LDHs and SDBS/Tween-LDHs. The surface free energy (ΔG⁰) and the dispersive component of the surface energy (γ_s^d) were estimated. The results show that the ΔG⁰ and γ_s^d of the modified LDHs are lower than that of MgAl-LDHs, ΔG⁰ and γ_s^d of the SDBS/Tween-LDHs are the lowest. This indicates that the chemical stability of SDBS/Tween-LDHs is better than that of other modified LDHs. In addition, the value of γ_s^d decreases with the increasing of temperature, so the compatibility with polymer can be improved by increasing the temperature in the preparation of polymer/hydrotalcite materials.
- hydrotalcite;surfactant;inverse gas chromatography;coumpounding modification
1. [1]
  [1] Kannan S. Catal. Surv. Asia, 2006, 10:117-137
2. [2]
  [2] Tsujimura A, Uchida M, Okuwaki A. J. Hazard Mater., 2007, 143:582-586
3. [3]
  [3] LIU Xiu-Fang(刘秀芳), FAN Bin-Bin(范彬彬), GAO Sheng-Cheng(高升成), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(2):345-349
4. [4]
  [4] Nejati K, Davary S, Saati M. Appl. Surf. Sci., 2013, 280:67-73
5. [5]
  [5] Sun Z M, Park Y, Zheng S L, et al. J. Colloid Interf. Sci., 2013, 408:75-81
6. [6]
  [6] FAN Ping(樊平), YANG Wei-Dong(杨维东), LI Hong-Ye(李宏业), et al. Environ. Sci. Technol.(环境科学与技术), 2011, 34(11):91-94
7. [7]
  [7] Erdogan B C, Ulku S. J. Porous Mat., 2013, 20:1143-1151
8. [8]
  [8] FENG Chun-Yao(冯春瑶), JIAO Qing-Ze(矫庆泽), LI Lie(李蕾), et al. Chin. J. Appl. Chem.(应用化学), 2001, 18(2):140-142
9. [9]
  [9] Jin X M, Liang J L, Yang C F, et al. J. Mater. Chem. B, 2013, 1:1921-1925
10. [10]
  [10] Zhang Y X, Long Y Y, Zhang Y C, et al. Appl. Clay Sci., 2012, 69:93-98
11. [11]
  [11] YANG Xue-Wen(杨学稳), ZHENG Jun-Ping(郑俊萍), SU Zheng-Tao(苏正涛), et al. Polym. Mater. Sci. Eng.(高分子材料科学与工程), 2002, 18(3):190-192
12. [12]
  [12] YU Ya-Chen(于雅晨), LI Kun-Lan(李坤兰), MA Ying-Chong(马英冲), et al. Chin. J. Chromatogr.(色谱), 2013, 31 (2):143-146
13. [13]
  [13] Maciejewska M, Krzywania-Kaliszewska A, Zaborski M. J. Chromatogr. A, 2012, 1257:141-148
14. [14]
  [14] WANG Qiang(王强), MA Feng-Yun(马凤云), TIAN Hua(田华), et al. Chin. J. Chromatogr.(色谱), 2011, 29(5):462-465
15. [15]
  [15] Reddy A S, Rani P R, Reddy K S. Polym. Eng. Sci., 2013, 53:1780-1785
16. [16]
  [16] Yazc D T. Surf. Interface Anal., 2010, 42:974-977
17. [17]
  [17] Yun S K, Pinnavaia T J. Chem. Mat., 1995, 7:348-354
18. [18]
  [18] Ruckriem M, Inayat A, Enke D, et al. Colloids Sur. A, 2010, 357:21-26
19. [19]
  [19] LIU Jin-Yan(刘金彦), HAN Wai-Hui(韩外慧), ZHANG Yan (张燕), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2010, 26(6):1552-1556
20. [20]
  [20] Hernandez M, Fenandez L, Borras C, et al. Anal. Chim. Acta, 2007, 597:245-256
21. [21]
  [21] XU Sheng(徐圣), ZHENG Hong-Yan(曾虹燕), ZHAO Ce(赵策), et al. J. Chin. Ceram. Soc.(硅酸盐学报), 2013, 41(4): 527-533
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
4. [4]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
5. [5]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
6. [6]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
7. [7]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
10. [10]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
11. [11]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
12. [12]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
13. [13]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
14. [14]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
15. [15]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
16. [16]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
19. [19]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
20. [20]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(371)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142