Citation: LIU Xi-Hui, ZHUO Xin, LIU Chao, LIU Tai-Zhu. Synthesis and Crystal Structure of Two 3D Networks Ni(Ⅱ)/Co(Ⅱ) Coordination Complexes Based on Bipyridine and Methanoic acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1128-1134. doi: 10.11862/CJIC.2014.142 shu

Synthesis and Crystal Structure of Two 3D Networks Ni(Ⅱ)/Co(Ⅱ) Coordination Complexes Based on Bipyridine and Methanoic acid

LIU Xi-Hui ^1,2 ,
ZHUO Xin ² ,
LIU Chao ² ,
LIU Tai-Zhu ²

1.
1 School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China;

Received Date: 30 April 2013
Available Online: 2 December 2013
Fund Project: 安徽省教育厅自然科学基金项目(No.KJ2011Z369，KJ2012A268，KJ2013A247)；安徽省优秀青年基金项目(No.2012SQRL207)；自旋电子与纳米材料安徽省重点实验室开放课题(No.2013YKF23，2011YKF02) (No.KJ2011Z369，KJ2012A268，KJ2013A247)；安徽省优秀青年基金项目(No.2012SQRL207)；自旋电子与纳米材料安徽省重点实验室开放课题(No.2013YKF23，2011YKF02)宿州学院纳米功能材料及应用创新团队(No.2013KYTD02)资助项目。 (No.2013KYTD02)

Two transition metal complexes, [M(bipy)(Metha)₂]_n·nH₂O (M=Ni, 1; Co, 2; bipy=4,4'-bipyridine, Metha=methanoic acid), have been synthesized by hydrothermal synthesis and characterized by elemental analyses, IR spectroscopy, and X-ray single-crystal diffraction etc. The single crystal structures show the two complexes belong to monoclinic system, C2/c space group. Complexes 1 and 2 have similar 3Dnetwork structures. Metha have two kinds of different types with M²⁺ ion, one kind is the two oxygen atoms of the Metha as bridging ligand atoms, connected by chain with bipy, another is the carboxyl oxygen of the Metha with only one oxygen atom with another M²⁺ ion.
- crystal structure;coordination complex;network structure
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