Citation: ZHANG Jin-Feng, ZHANG Ji-Yao, ZHAO Jian-She, ZHANG Cun-She, SHEN Han-Xi, ZHOU Kui. Preparation, Characterization and Catalytic Performance of Ti-Co-SBA-15 Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1063-1067. doi: 10.11862/CJIC.2014.138 shu

Preparation, Characterization and Catalytic Performance of Ti-Co-SBA-15 Catalysts

1.
1 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China;

Received Date: 27 August 2013
Available Online: 3 December 2013

Aseries of Ti-SBA-15 with different titanium loadings were synthesized under conventional hydrothermal conditions, using tetra-n-butyl titanate as the titanium source. The Ti-Co-SBA-15 catalysts were synthesized by using the impregnation method. The catalyst samples were characterized using XRD, UV-Raman, FTIR, low temperature N₂ adsorption-desorption. The catalytic performance of the catalysts was evaluated for oxidation of 4-tert-butyltoluene into 4-tert-butylbenzaldehyde under mild conditions. The results show that the prepared catalysts have larger surface area and pore size, and they contain four coordinated titanium and cobalt. The catalysts have higher activity, selectivity and yield of 4-tert-butylbenzaldehyde in the oxidation reaction of 4-tert-butyltoluene.
- Ti-Co-SBA-15;molecular sieve;4-tert-butyltoluene;selective oxidation;4-tert-butylbenzaldehyde
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沈阳化工大学材料科学与工程学院沈阳 110142