Citation: ZHANG Qi-Long, FENG Guang-Wei, WANG Li, WANG Zheng, ZHU Bi-Xue. Synthesis, Crystal Structure and Antibacterial Activity of Schiff Base Ni(Ⅱ) Complexes Containing Schiff Base and Imidazole[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1025-1030. doi: 10.11862/CJIC.2014.130 shu

Synthesis, Crystal Structure and Antibacterial Activity of Schiff Base Ni(Ⅱ) Complexes Containing Schiff Base and Imidazole

1.
1 Department of Chemistry, Guiyang Medical College, Guiyang 550004, China;

Received Date: 17 May 2013
Available Online: 31 October 2013
Fund Project: 国家自然科学基金(No.21061003)；贵州省联合基金(黔科合LG字[2012]016)；贵阳医学院青年基金资助项目。 (No.21061003)；贵州省联合基金(黔科合LG字[2012]016)

The two nickel (Ⅱ) complexes [Ni(L)(Himdz)](1)、[Ni(L)(Mimdz)](2) were synthesized from the reaction of tridentate Schiff base (1-phenyl-3-[(2-hydroxyphenyl)imino]-1-butanone) (H₂L) and monodentate N-heterocycles [imidazole (Himdz), 2-methylimidazole (Mimdz)] with Ni(OAc)₂·4H₂O and characterized by elemental analysis, IR, ¹H NMR spectroscopy. An X-ray structure determination of the complexes has been completed. In the solid state, both [Ni(L)(Himdz)] (1), [Ni(L)(Mimdz)] (2) crystallize in P2₁/c space groups, and exist as dimers due to intermolecular C-H…π interactions. Each of the dimeric molecules forms a one-dimensional zigzag chain via intermolecular N-H…O hydrogen bonds involving the heterocycle N-H group, respectively. The antibacterial activities of the ligand and complexes were tested against seven kinds of bacteria. The results show that the complexes 1 and 2 possess inhibiting effects.
- Ni(Ⅱ)Complex;crystal structure;hydrogen bonds;antibactenal activity
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沈阳化工大学材料科学与工程学院沈阳 110142