Citation: YAN Bo, ZHANG Jin-Qiu, YANG Pei-Xia, AN Mao-Zhong. Effect of 2-Butyne-1,4-diol and Ethylene Diamine on Electrodeposition of Cu from Ionic Liquid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 952-960. doi: 10.11862/CJIC.2014.121 shu

Effect of 2-Butyne-1,4-diol and Ethylene Diamine on Electrodeposition of Cu from Ionic Liquid

1.
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: AN Mao-Zhong,
Received Date: 1 November 2013
Available Online: 9 December 2013
Fund Project: 国家自然科学基金(No.51074057)资助项目。 (No.51074057)

The effect of additives, 2-Butyne-1,4-diol (BDO) and ethylene diamine (EDA), was investigated on the electrodeposition of Cu from 1-hexyl-3-methylimidazolium trifluoromethanesulfonate ([HMIM]OTF). The results of UV-Vis absorption spectra and Cyclic voltammograms indicate that the reduction potential of Cu shifts to the positive side with the addition of BDO without any changes in the coordination environment of Cu²⁺. The adsorption of BDO on surface of working electrode results in a change in morphology of the obtained deposit. In the presence of EDA, the coordination environment of Cu²⁺ is changed, suggesting the formation of a new complex by Cu²⁺ and EDA. The deposition potential shifts to the positive side with addition of EDA. Scanning electron microscope and atomic force microscope tests show that the surface morphology of the obtained deposit is flatter and more granular compared to that without EDA. When BDO and EDA are added into [HMIM]OTF at the same time, the deposition potential still shifts positively and nano-sized grains are obtained.
- ionic liquid;2-butyne-1,4-diol;ethylene diamine;electrodepositon;Cu
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沈阳化工大学材料科学与工程学院沈阳 110142