Citation: DU Shang-Chao, TAN Hua-Qiao, BI Yan-Feng, YU Yang, LIAO Wu-Ping. Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene：Syntheses, Structures and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 749-756. doi: 10.11862/CJIC.2014.112 shu

Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene：Syntheses, Structures and Magnetic Property

1.
1 State Key Laboratory of Rare Earth Resource Utilization; Engineering Research Center for the Separation and Purification of REs and Thorium; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

Corresponding author: LIAO Wu-Ping,
Received Date: 13 July 2013
Available Online: 20 November 2013
Fund Project: 国家自然科学基金(21221061,51222404,51074148,91026024) (21221061,51222404,51074148,91026024)973项目(2012CBA01206)资助项目。 (2012CBA01206)

Three compounds, [Co₂Th₄(HC8A)₂O₂(OH)₂(DMF)₆](1)、[Ni₂Th₅(H₂C8A)(C8A)O₄(OH)₂(DMF)₅(CH₃OH)₂](2)、[Zn₂Th₆(HC8A)(C8A)O₅(CH₃O)(C₃H₆NO₂)₂(DMF)₅(CH₃OH)](3) (H₈C8A=p-tert-butylcalix[8]arene, DMF=N,N-dimethylformide), were obtained by solvothermal method and characterized by single crystal X-ray diffraction, element analysis, and so on. All these three structures are featured by some sandwich-like units which are constructed by two tail-to-tail calix[8]arene molecules and one in-between 3d-5f polynuclear core. All the calix[8]-arene molecules adopt a double-cone conformation, each cone of calix[8]arene molecule bonds one thorium cation by its lower rim, and two cones of one calixarene molecule is connected by some thorium or transition metal atoms. Magnetic measurement indicates that compound 1 exhibits weak ferromagnetic interaction between the metals at low temperature.
- calixarenes;thorium;3d-5f cluster compounds;crystal structure;magnetic property
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