Citation: WANG Shu-Ju, TIAN Yan-Wen, YOU Li-Xin, DING Fu, SUN Ya-Guang. Synthesis, Structure and Luminescent Properties of Two Zinc Coordination Polymers Based on Biphenyl-3,3’,5-tricarboxylic and 2,6-Bis(imidazole-1-yl)pyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 511-516. doi: 10.11862/CJIC.2014.096 shu

Synthesis, Structure and Luminescent Properties of Two Zinc Coordination Polymers Based on Biphenyl-3,3’,5-tricarboxylic and 2,6-Bis(imidazole-1-yl)pyridine Ligands

1.
1 Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, China;

Received Date: 10 April 2013
Available Online: 9 November 2013
Fund Project: 国家自然科学基金(No.21071100) (No.21071100)辽宁省博士启动基金(No.20111046)资助项目。 (No.20111046)

Two coordination polymers, {[Zn₃(H₂O)₇(bpta)₂]·5H₂O}_n (1) (H₃bpta=biphenyl-3,3',5-tricarboxylic acid) and {[Zn₂Cl(bpta)(bip)₂]·2H₂O}_n (2) [bip=2,6-bis(imidazole-1-yl)pyridine], have been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. Complex 1 crystallizes in monoclinic system, space group C2/c with a=3.317 1(11) nm, b=1.495 7(5) nm, c=0.695 1(2) nm, β=91.50°, Z=4. Complex 2 crystallizes in monoclinic, space group P2/c with a=1.960 4(4) nm, b=1.035 7(2) nm, c=1.998 7(4) nm, β=101.97(3)°, Z=4. For 1, Zn(Ⅱ) bridged by bpta ligands to form a 1D chain, through the hydrogen bonding interaction between water molecules and carboxylate oxygen atoms, further extend 1D chains into a 3D structure. For 2, Zn(Ⅱ) were linked by bip ligands to form a 1D helical chain, and 1D chains further connected by bpta ligands to form 2D network. In addition, TG and luminescent properties of two complexes have also been investigated.CCDC: 929651, 1; CCDC: 929652, 2.
- coordination polymers;crystal structure;biphenyl-3,3’,5-tricarboxylic acid;2,6-bis(imidazole-1-yl)pyridine
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沈阳化工大学材料科学与工程学院沈阳 110142