Citation: CHENG Xiao-Ning*, ZHANG Wei-Xiong, XUE Wei, CHEN Xiao-Ming*. Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 142-148. doi: 10.11862/CJIC.2014.087 shu

Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate

1.
1 MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China;

Received Date: 27 September 2013
Available Online: 27 November 2013
Fund Project:

Three isostructural coordination polymers, namely [Ni(8-qoac)Cl]_n (1, 8-Hqoac=quinoline-8-oxy-acetic acid), [Fe(8-qoac)Cl]_n (2), and [Mn(8-qoac)Cl]_n (3) were synthesized under solvothermal reaction conditions. Single-crystal X-ray diffraction studies showed that 1~3 crystallize in the same space group Pbca, in which the octahedral metal ions are first bridged by two chloride ions to form a dinuclear building blocks, and then each dinuclear building block is connected to four adjacent neighbors via four carboxylate groups with the anti-anti coordination mode, giving a two-dimensional layered (4, 4) network considering the dinuclear building blocks as 4-connected nodes and the carboxylate groups as linkers. Magnetic measurements revealed spin-canting-like behaviors for compound 1, while 2 and 3 only exhibit simple antiferromagnetic properties, which can be explained by the different magnetic anisotropic behaviors of the transition metal ions.
- coordination polymer;isostructure;laminate;magnetism;spin canting,
1. [1]
  [1] Kurmoo M, Kumagai H, Akita-Tanaka M, et al. Inorg. Chem., 2006, 45:1627-1637
2. [2]
  [2] Ruben M, Rojo J, Romero-Salguero F J, et al. Angew. Chem. Int. Ed., 2004, 43:3644-3662
3. [3]
  [3] Kitagawa S, Uemura K. Chem. Soc. Rev., 2005, 34:109-119
4. [4]
  [4] Zheng Y Z, Xue W, Zheng S L, et al. Adv. Mater., 2008, 20: 1534-1538
5. [5]
  [5] Wang X Y, Wei H Y, Wang Z M, et al. Inorg. Chem., 2005, 44:572-583
6. [6]
  [6] Escuer A, Cano J, Goher M A S, et al. Inorg. Chem., 2000, 39:4688-4695
7. [7]
  [7] Cheng X N, Zhang W X, Chen X M. J. Am. Chem. Soc., 2007, 129:15738-15739
8. [8]
  [8] Cheng X N, Xue W, Huang J H, et al. Dalton Trans., 2009: 5701-5707
9. [9]
  [9] Koelsch C F. J. Am. Chem. Soc., 1931, 53:304-305
10. [10]
  [10] Christopher J C, Carrell H L, Jonah E, et al. J. Am. Chem. Soc., 1988, 110:8651-8656
11. [11]
  [11] Lefebvre J, Trudel S, Hill R H, et al. Chem. Eur. J., 2008, 14:7156-7167
12. [12]
  [12] LIU Zhong-Yi(刘忠义), LIU Jing(刘婧), YANG Na(杨娜), et al. Science China(中国科学:化学), 2013, 43:1251-1261
13. [13]
  [13] Fisher M E. Am. J. Phys., 1964, 32:343-351
14. [14]
  [14] Bai S Q, Gao E Q, He Z, New J. Chem., 2005, 29:935-941
1. [1]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
2. [2]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
3. [3]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
4. [4]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
5. [5]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
6. [6]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
9. [9]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
10. [10]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
13. [13]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
16. [16]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
17. [17]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
18. [18]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
19. [19]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
20. [20]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234

Get Citation

PDF

XML

Metrics

PDF Downloads(513)
Abstract views(786)
HTML views(100)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com