Citation: MA Zhi-Feng, ZHANG Ying-Hui, HU Tong-Liang*, BU Xian-He. Three Cobalt(Ⅱ) Complexes Based on Isomeric Carboxylate-Based Flexible Ligands：Syntheses, Structures and Magnetism[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 204-212. doi: 10.11862/CJIC.2014.078 shu

Three Cobalt(Ⅱ) Complexes Based on Isomeric Carboxylate-Based Flexible Ligands：Syntheses, Structures and Magnetism

1.
Department of Chemistry, and Tianjin Key Laboratory of Metal & Molecule-based Material Chemistry, Nankai University, Tianjin 300071, china

Received Date: 18 November 2013
Available Online: 30 November 2013
Fund Project:

Three Co(Ⅱ) complexes based on E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H₂L¹) or E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H₂L²), namely [Co(L¹)(bpp)]_n(1), {[Co(μ₃-OH)₂(L²)₄(bpy)₂(H₂O)₄]·12H₂O}_n (2), and [Co(L²)(bpy)]_n(3) (bpp: 1,3-bi(pyridin-4-yl)propane, bpy: 4,4-bipyridine), were synthesized and characterized by elemental analysis, IR, XRPD and X-ray single-crystal structure analysis. Different coordination environment for Co(Ⅱ) ions and thereby different crystal structures and magnetism were observed for these three complexes. The magnetic properties of complexes 1 and 2 were discussed in detail.
- cobalt(Ⅱ) complexes;flexible ligands;crystal structure;magnetic property,
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沈阳化工大学材料科学与工程学院沈阳 110142