Citation: XIAO Chong, LI Zhou, XIE Yi*. Synergistic Optimization of Electrical and Thermal Transport Properties in Chalcogenides Thermoelectric Materials[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 10-19. doi: 10.11862/CJIC.2014.071 shu

Synergistic Optimization of Electrical and Thermal Transport Properties in Chalcogenides Thermoelectric Materials

1.
Hefei National Laboratory for Physical Sciences at the Microscale, and Collaborative Innovation Center of Chemistry for Energy Materials, University of Science & Technology of China, Hefei 230026, China

Received Date: 27 September 2013
Available Online: 6 November 2013
Fund Project:

Over the past few years, thermoelectric materials have redrawn considerable attentions among physics, chemistry, and materials researchers due to their capability of direct conversion between heat and electricity, which is today well recognized as viable renewable-energy sources. However, it is still one of the biggest challenges hitherto to independently optimize these three parameters for obtaining high-performance thermoelectric materials with large ZT value. Chalcogenide semiconductors as the most important class of thermoelectric materials, the synergistic optimization of their electrical-thermal transport properties has attracted widespread attentions. Herein, we reviewed the latest development of the synergistic optimization in Chalcogenide semiconductors. We also analyzed the inherent physical mechanisms within the synergistic optimization. Finally, we summarized the prospects of these new strategies in thermoelectric materials development.
- chalcogenides semiconductors;thermoelectric materials;synergistic optimization,
1. [1]
  [1] Wise M, Calvin K, Thomson A, et al. Science, 2009, 324 (5931):1183-1186
2. [2]
  [2] Wood C. Rep. Prog. Phys., 1988, 51(4):459-539
3. [3]
  [3] Bell L E. Science, 2008, 321(5895):1457-1461
4. [4]
  [4] Tritt T M. Annu. Rev. Mater. Res., 2011, 41:433-448
5. [5]
  [5] Tritt T M, Subramanian M A. MRS Bull., 2006, 31(3):188-198
6. [6]
  [6] Snyder G J, Toberer E S. Nat. Mater., 2008, 7(2):105-114
7. [7]
  [7] Shakouri A. Annu. Rev. Mater. Res., 2011, 41:399-431
8. [8]
  [8] Mahan G D, Bartkowiak M. Appl. Phys. Lett., 1999, 74(7): 953-954
9. [9]
  [9] Rao C N R. Acc. Chem. Res., 1984, 17(3):83-89
10. [10]
  [10] Imada M, Fujimori A, Tokura Y. Rev. Modern. Phys., 1998, 70(4):1039-1263
11. [11]
  [11] Wu C Z, Feng F, Feng J, et al. J. Am. Chem. Soc., 2011, 133(35):13798-13801
12. [12]
  [12] Kobayashi M. Solid State Ionics., 1990, 39(3-4):121-149
13. [13]
  [13] Santhosh K M C, Pradeep B. Semicond. Sci. Technol., 2002, 17(3):261-265
14. [14]
  [14] Wiegers G A. Am. Mineral., 1971, 56(11-12):1882-1888
15. [15]
  [15] Billetter H, Ruschewitz U. Z. Anorg. Allg. Chem., 2008, 634 (2):241-246
16. [16]
  [16] Xiao C, Xu J, Li K, et al. J. Am. Chem. Soc., 2012, 134(9): 4287-4293
17. [17]
  [17] Xiao C, Qin, X M, Zhang J, et al. J. Am. Chem. Soc., 2012, 134(44):18460-18466
18. [18]
  [18] Slack G A. CRC Handbook of Thermoelectric. Boca Raton: Chemical Rubber, 1995.
19. [19]
  [19] Snyder G J, Christensen M, Nishibor E, et al. Nat. Mater., 2004, 3(7):458-463
20. [20]
  [20] Xiao C, Xu J, Cao B X, et al. J. Am. Chem. Soc., 2012, 134 (18):7971-7977
21. [21]
  [21] Goto Y, Naito F, Sato R. Inorg. Chem., 2013, 52(17):9861-9866
22. [22]
  [22] Liu H L, Shi X, Xu F F, et al. Nat. Mater., 2012, 11(5):422-425
23. [23]
  [23] Larson P, Mahanti S D, Kanatzidis M G. Phys. Rev. B, 2000, 61(12):8162-8171
24. [24]
  [24] Youn S J, Freeman A J. Phys. Rev. B, 2000, 63(8):085112
25. [25]
  [25] Sun Y F, Cheng H, Gao S, et al. J. Am. Chem. Soc., 2012, 134(50):20294-20297
26. [26]
  [26] Hicks L D, Harman T C, Dresselhaus M S. Appl. Phys. Lett., 1993, 63(23):3230-3232
27. [27]
  [27] Klemens P G. Proc. Phys. Soc. London Sec. A, 1955, 68(12): 1113-1128
28. [28]
  [28] Carruthers P. Rev. Mod. Phys., 1961, 33(1):92-138
29. [29]
  [29] Dismukes J P, Ekstrom L, Steigmeier E F, et al. J. Appl. Phys., 1964, 35(10):2899-2907
30. [30]
  [30] Slack G A, Hussain M A. J. Appl. Phys., 1991, 70(5):2694-2718
31. [31]
  [31] Cahill D G, Watanabe F, Rockett A, et al. Phys. Rev. B, 2005, 71(23):235202
32. [32]
  [32] Yu C, Scullin M L, Huijben M, et al. Appl. Phys. Lett., 2008, 92(19):191911
33. [33]
  [33] Vineis C J, Shakouri A, Majumdar A, et al. Adv. Mater., 2010, 22(36):3970-3980
34. [34]
  [34] Rowe D M, Shukla V S, Savvides N, Nature, 1981, 290(5809): 765-766
35. [35]
  [35] Vining C B, Laskow W, Hanson J O, et al. J. Appl. Phys., 1991, 69(8):4333-4340
36. [36]
  [36] Chen G. Phys. Rev. B, 1998, 57(23):14958-14973
37. [37]
  [37] Mi J L, Zhu T J, Zhao X B, et al. J. Appl. Phys., 2007, 101 (5):054314
38. [38]
  [38] Bux S K, Blair R G, Gogna P K, et al. Adv. Funct. Mater., 2009, 19(12):2445-2452
39. [39]
  [39] Biswas K, He J Q, Blum I D, et al. Nature, 2012, 489(7416): 414-418
40. [40]
  [40] Disalvo F J. Science, 1999, 285(5428):703-706
41. [41]
  [41] Goldsmid H J. Thermoelectric Refrigeration. New York: Plenum Press, 1964.
42. [42]
  [42] Ravich Y I, Efimova B A, Smirnov I A. Semiconducting Lead Chalcogenides. New York: Plenum Press, 1970.
43. [43]
  [43] Sitter H, Lischka K, Heinrich H. Phys. Rev. B, 1977, 16(2): 680-687
44. [44]
  [44] Ravich Y I. In Lead Chalcogenides: Physics and Applica-tions: Ch.1. New York: Taylor & Fransics Group, 2003.
45. [45]
  [45] Hoang K S, Mahanti D, Kanatzidis M G. Phys. Rev. B, 2010, 81(11):115106
46. [46]
  [46] Pei Y Z, Shi X, LaLonde A, et al. Nature, 2011, 473(7345): 66-69
47. [47]
  [47] Rhyee J S, Lee K H, Lee S M, et al. Nature, 2009, 459(7249): 965-968
48. [48]
  [48] Rhyee J S, Ahn K, Lee K H, et al. Adv. Mater., 2011, 23 (19):2191-2194
49. [49]
  [49] Zhu G H, Lan Y C, Wang H, et al. Phys. Rev. B, 2011, 83 (11):115201
50. [50]
  [50] Kim J H, Rhyee J S, Kwon Y S. Phys. Rev. B, 2012, 86(23): 235101
51. [51]
  [51] Ahn K, Cho E, Rhyee J S, et al. J. Mater. Chem., 2012, 22 (12):5730-5736
52. [52]
  [52] Alivisatos A P. Science, 1996, 271(5251):933-937
53. [53]
  [53] Dresselhaus M S, Chen G, Tang M Y, et al. Adv. Mater., 2007, 19(8):1043-1053
54. [54]
  [54] Brus L E. J. Phys. Chem., 1986, 90(12):2555-2560
55. [55]
  [55] Henglein A. Top. Curr. Chem., 1988, 143:113-119
56. [56]
  [56] Steigerwald M L, Brus L E. Annu. Reu. Mater. Sci., 1989, 19:471-495
57. [57]
  [57] Steigerwald M L, Brus L E. Acc. Chem. Res., 1990, 23(6): 183-188
58. [58]
  [58] Halperin W P. Rev. Mod. Phys., 1986, 58(3):533-606
59. [59]
  [59] Ball P, Garwin L. Nature, 1992, 355:761-766
60. [60]
  [60] Goldstein A N, Echer C M, Alivisatos A P. Science, 1992, 256(5062):1425-1427
61. [61]
  [61] Harman T C, Taylor P J, Walsh M P, et al. Science, 2002, 297(5590):2229-2232
62. [62]
  [62] Ikeda T, Collins L A, Ravi V A, et al. Chem. Mater., 2007, 19(4):763-767
63. [63]
  [63] Zhao Y, Dyck J S, Hernandez B M, et al. J. Am. Chem. Soc., 2010, 132(14):4982-4983
64. [64]
  [64] Chen J, Zhang G, Li B W. Nano Lett., 2010, 10(10):3978-3983
65. [65]
  [65] Scheele M, Oeschler N, Veremchuk I, et al. ACS Nano, 2010, 4(7):4283-4291
66. [66]
  [66] Poudeu P F P, Güeguen A, Wu C I, et al. Chem. Mater., 2010, 22(3):1046-1053
67. [67]
  [67] Zhang Y C, Wang H, Kraemer S, et al. ACS Nano, 2011, 5 (4):3158-3165
68. [68]
  [68] Soni A, Zhao Y Y, Yu L G, et al. Nano Lett., 2012, 12(3): 1203-1209
69. [69]
  [69] Soni A, Shen Y Q, Yin M, et al. Nano Lett., 2012, 12(8): 4305-4310
70. [70]
  [70] Mehta R J, Zhang Y L, Karthik C, et al. Nat. Mater., 2012, 11(3):233-240
71. [71]
  [71] Liu Y, Zhao L D, Liu Y C. J. Am. Chem. Soc., 2011, 133 (50):20112-20115
72. [72]
  [72] Pei Y L, He J Q, Li J F. NPG Asia Mater., 2013, 5:e47
73. [73]
  [73] Li F, Li J F, Zhao L D. Energy Environ. Sci., 2012, 5(5): 7188-7195
74. [74]
  [74] Li J, Sui J H, Pei Y L. Energy Environ. Sci., 2012, 5(9):8543-8547
75. [75]
  [75] Barreteau C, Berardan D, Amzallag E. Chem. Mater., 2012, 24(16):3168-3178
1. [1]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
4. [4]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
5. [5]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
6. [6]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . 原位电化学阻抗谱监测长寿命热电池Nb₁₂WO₃₃正极材料的高温双放电机制. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-. doi: 10.1016/j.actphy.2024.100040
7. [7]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
8. [8]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
9. [9]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
10. [10]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
11. [11]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
14. [14]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
15. [15]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
16. [16]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
17. [17]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
18. [18]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
19. [19]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
20. [20]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290

Get Citation

PDF

XML

Metrics

PDF Downloads(599)
Abstract views(1092)
HTML views(135)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142