N-杂环卡宾化合物的合成及其在有机合成中的应用

刘波 陈万芝*

引用本文: 刘波, 陈万芝*. 铜N-杂环卡宾化合物的合成及其在有机合成中的应用[J]. 无机化学学报, 2014, 30(1): 20-36. doi: 10.11862/CJIC.2014.068 shu
Citation:  LIU Bo, CHEN Wan-Zhi*. Synthesis and Applications of Copper N-heterocyclic Carbene Complexes[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(1): 20-36. doi: 10.11862/CJIC.2014.068 shu

N-杂环卡宾化合物的合成及其在有机合成中的应用

  • 基金项目:

    国家自然科学基金(No.20872129,21072170)资助项目。 

摘要: N-杂环卡宾铜化合物具有简便易得,价廉低毒,性质稳定,结构类型多样并易于修饰等诸多优点,在很多领域具有重要的应用价值,因此铜的N-杂环卡宾化学在过去十几年中得到了快速发展。本文结合我们的工作,总结铜N-杂环卡宾化合物的合成方法、结构特点、转移卡宾配体用于合成其它金属卡宾化合物以及催化应用。

English

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  • 收稿日期:  2013-09-30
  • 网络出版日期:  2013-11-05
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