Citation: SUN Li-Ping, ZHAO Hui, WANG Wen-Xue, LI Qiang, HUO Li-Hua. Electrochemical Performance of La₂CuO₄ Nanotube Materials Prepared via Electrospinning Method[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 757-762. doi: 10.11862/CJIC.2014.044 shu

Electrochemical Performance of La₂CuO₄ Nanotube Materials Prepared via Electrospinning Method

1.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Corresponding author: ZHAO Hui,
Received Date: 11 June 2013
Available Online: 10 October 2013
Fund Project: 国家自然科学基金(No.51072048,51102083)；黑龙江省杰出青年科学基金(JC201211) (No.51072048,51102083)；黑龙江省杰出青年科学基金(JC201211)黑龙江省自然科学基金(B201107)资助项目。 (B201107)

La₂CuO₄ nanotubes are successfully synthesized by electro-spinning technology. The structure and morphology of the materials are characterized by XRD, TG-DTA and SEM, respectively. The results show that La₂CuO₄ nanotubes with an average diameter of 150 nm are obtained after sintering at 700 ℃ for 2 h. The La₂CuO₄ nanotube forms sufficient connection with each other, and good contact with the electrolyte after sintering at 900 ℃ for 0.5 h. Comparing the results obtained by Electrochemical Impedance Spectroscopy (EIS), it is clearly observed that the nanotube cathode exhibits superior performance than the powder cathode. The area specific resistance (ASR) of the nanotube cathode is 1.03 Ω·cm² at 700 ℃ in air, whereas for the powder one with the same composition, the ASRis 1.61 Ω·cm². The oxygen partial pressure measurement indicates that the charge transfer process is the rate-limiting step of the nanotube electrode reactions.
- La₂CuO₄ nanotubes;Intermediate temperature solid oxide fuel cell (ITSOFC);cathode materials;electrode reaction
1. [1]
  [1] Liu M L, Lynch M E, Blinn K, et al. Materialstoday, 2011, 14(11):534-546
2. [2]
  [2] Zhou W, Ran R, Shao Z P. J. Power Sources, 2009, 192:231-246
3. [3]
  [3] Huang J B, Xie F C, Wang C, et al. Int. J. Hydrogen Energy, 2012, 37:877-883
4. [4]
  [4] Tietz F, Mai A, Stver D. Solid State Ionics, 2008, 179:1509-1515
5. [5]
  [5] Kivi I, Mller P, Kurig H, et al. Electrochem. Commun., 2008, 10:1455-1458
6. [6]
  [6] Zhu X B, Ding D, Li Y Q, et al. Int. J. Hydrogen Energy, 2013, 38:5375-5382
7. [7]
  [7] Gao Z, Mao Z Q, Wang C, et al. Int. J. Hydrogen Energy, 2011, 36:7229-7233
8. [8]
  [8] Ortiz-Vitoriano N, Ruiz de Larramendi I, Ruiz de Larramendi I J, et al. J. Power Sources, 2009, 192:63-69
9. [9]
  [9] Suzuki T, Takahashi Y, Hamanoto K, et al. Int. J. Hydrogen Energy, 2011, 36:10998-11003
10. [10]
  [10] Sun L P, Zhao H, Li Qiang, et al. Int.J. Hydrogen Energy, 2011, 36:12555-12560
11. [11]
  [11] Li Q, Sun L P, Huo L H, et al. J. Solid State Electrochem., 2012, 16:1169-1174
12. [12]
  [12] Li Q, Sun L P, Huo L H, et al. J. Power Sources, 2011, 196: 1712-1716
13. [13]
  [13] Pinedo R, Ruiz de Larramendi I, Jimenez de Aberasturi D, et al. J. Power Sources, 2011, 196:4174-4180
14. [14]
  [14] Sacanell J, Bellino M G, Lamas D G, et al. Physica B, 2007, 398:341-343
15. [15]
  [15] Sacanell J, Leyva A G, Bellino M G, et al. J. Power Sources, 2010, 195:1786-1792
16. [16]
  [16] Zhang N Q, Li J, He Z L, et al. Electrochem. Commun., 2011, 13:570-573
17. [17]
  [17] Sun L P, Li Q, Zhao H, et al. Int. J. Hydrogen Energy, 2012, 37:11955-11962
18. [18]
  [18] Gao L Z, Chua H T, Kawi S. J. Solid State Chemistry, 2008, 181:2804-2807
19. [19]
  [19] Yuan J, Dai H X, Zhang L, et al. Catal. Today, 2011, 175: 209-215
20. [20]
  [20] Chen L, Dong C, Huang Y Z, et al. Solid State Commun, 2000, 114:107-111
21. [21]
  [21] Hirayama T, Nakagava M, Oda Y. Solid State Sciences, 2000, 113:121-124
22. [22]
  [22] Zhao H, Huo L H, Gao S. J. Power Sources, 2004, 125:149-154
23. [23]
  [23] Bebelis S, Kotsionopoulos N, Mai A, et al. Solid State Ionics, 2006, 177:1843-1848
24. [24]
  [24] Zhan G, Liu X M, Bergman B, et al. J. Power Sources, 2011, 196:9195-9203
25. [25]
  [25] Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001, 143:379-389
1. [1]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
2. [2]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
3. [3]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
4. [4]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
5. [5]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
6. [6]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
7. [7]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
8. [8]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
9. [9]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
10. [10]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
11. [11]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
12. [12]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . 电容去离子提锂技术中电极材料的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-. doi: 10.1016/j.actphy.2025.100089
13. [13]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
14. [14]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-. doi: 10.1016/j.actphy.2025.100085
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
19. [19]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
20. [20]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(367)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Performance of La2CuO4 Nanotube Materials Prepared via Electrospinning Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of La₂CuO₄ Nanotube Materials Prepared via Electrospinning Method