Citation: WANG Jing-Lin, JIAO Yong, YANG Bin-Sheng. Supramolecule Assembled from Sulfonyl Hydrazone Ni(Ⅱ) Complex via π…π and C-H…π Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 411-418. doi: 10.11862/CJIC.2014.030 shu

Supramolecule Assembled from Sulfonyl Hydrazone Ni(Ⅱ) Complex via π…π and C-H…π Interactions

1.
1 Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China;

Corresponding author: YANG Bin-Sheng,
Received Date: 24 April 2013
Available Online: 28 July 2013
Fund Project:

An intriguing supramolecular complex NiL₂ (HL: (E)-4-methyl-N'-(pyridin-2-ylmethylene) benzenesul-fonohydrazide) with novel Ni-O (sulfonyl) coordination bond has been synthesized and characterized. The structural studies indicate that two types of dimers are assembled via intermolecular offset face-to-face π…π stacking (OFF) and edge-to-face C-H…π (EF) interactions between two pyridyl rings in the crystal structure of NiL₂. Each dimer exists in two enantiomeric forms. The DFTcalculation indicates that the parallel fourfold aryl embrace (P4AE) interactions, with one OFFinteraction and two EFinteractions, are stronger than that of only OFF, which can be called synergistic effects. The spectral studies show that the ratio of Ni(Ⅱ) to HLis 1:2 in this compound. CCDC: 773667.
- sulfonyl hydrazone;Ni(Ⅱ) complex;crystal structure;π…π interaction;DFT calculation
1. [1]
  [1] Steed J W, Atwood J L. Supramolecular Chemistry. 2nd Ed. Chichester: John Wiley & Sons, Ltd., 2009:2-9
2. [2]
  [2] Leininger S, Olenyuk B, Stang P J. Chem. Rev., 2000,100: 853-908
3. [3]
  [3] LI Zheng(李正), ZHAO Yue(赵越), WANG Peng(王鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(7): 1469-1476
4. [4]
  [4] Huang W, Zhu H B, Gou S H. Coord. Chem. Rev., 2006, 250:414-423
5. [5]
  [5] Tiefenbacher K, Rebek Jr J. J. Am. Chem. Soc., 2012,134: 2914-2017
6. [6]
  [6] Desiraju G R. Angew. Chem. Int. Engl., 1995,34:2311-2327
7. [7]
  [7] NI Zhong-Hai(倪中海), NIE Jing(聂景), LI Guo-Ling(李国玲), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(2):411-416
8. [8]
  [8] Quiñonero D, Frontera A, Escudero D, et al. Theor. Chem. Account, 2008,120:385-393
9. [9]
  [9] Wei W, Wu M, Gao Q, et al. Inorg. Chem., 2009,48:420-422
10. [10]
  [10] Dance I, Scudder M. CrystEngComm, 2009,11:2233-2247
11. [11]
  [11] Russell V, Scudder M, Dance I. J. Chem. Soc., Dalton Trans., 2001:789-799
12. [12]
  [12] McMurtrie J, Dance I. CrystEngComm, 2005,7:216-229
13. [13]
  [13] Dance I. New J. Chem., 2003,27:22-27
14. [14]
  [14] Dance I. CrystEngComm, 2003,5:208-221
15. [15]
  [15] Lacour J, Bernardinelli G, Russell V, et al. CrystEngComm, 2002,4(30):165-170
16. [16]
  [16] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896
17. [17]
  [17] Wang J, Liu B, Yang B. CrystEngComm, 2011,13:7086- 7097
18. [18]
  [18] Döring M, Görls H, Uhlig E. Z. Anorg. Allg. Chem., 1992, 613:55-59
19. [19]
  [19] Larabi L, Harek Y, Reguig A, et al. J. Serb. Chem. Soc., 2003,68(2):85-95
20. [20]
  [20] (a)SMART (control) and SAINT (integration) Software, Bruker Analytical X-ray Systems, Madison, WI, 1994. (b)Bruker, SMART(Version 5.0) and SAINT (Version 6.02), Bruker AXS Inc., Madison, Wisconsin, USA, 2000.
21. [21]
  [21] Sheldrick G M. SADABS, A Program for Absorption Corrections, University of Göttingen, Germany, 1996.
22. [22]
  [22] Sheldrick G M. SHELXL97, A Program for the Refinement of Crystal Structures from X-ray Data, University of Göttingen, Germany, 1997.
23. [23]
  [23] Klaus B. DIAMOND, Version 1.2c, University of Bonn, Germany, 1999.
24. [24]
  [24] Frisch M J, Trucks G W, Schlegel H B, et al. Gaussian 03, Gaussian Inc., Pittsburgh, PA, 2003.
25. [25]
  [25] Chavarot M, Ménage S, Hamelin O, et al. Inorg. Chem., 2003,42:4810-4816
26. [26]
  [26] Li M, Sun Q, Bai Y, et al. Dalton Trans., 2006:2572-2578
27. [27]
  [27] Zuccaccia D, Bellachioma G, Cardaci G, et al. Dalton Trans., 2006:1963-1971
28. [28]
  [28] Gao E Q, Yue Y F, Bai S Q, et al. J. Am. Chem. Soc., 2004,126:1419-1429
29. [29]
  [29] Lakowicz J R. Principles of Fluorescence Spectroscopy. 3rd. Ed. New York: Springer Science+Business Media, LLC, 2006:334-338
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沈阳化工大学材料科学与工程学院沈阳 110142