Citation: HAN Qi-Wei, ZHU Bao-Lin, TIAN Jing, SONG Juan-Juan, HU Xiao-Jing, SHI Yu-Kun, HUANG Wei-Ping. Synthesis and Catalytic Performance for CO Oxidation of CuO Modified-TiO₂ Nanotubes with High Thermal Stability via Functionalized Sol Modification[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 573-578. doi: 10.11862/CJIC.2014.026 shu

Synthesis and Catalytic Performance for CO Oxidation of CuO Modified-TiO₂ Nanotubes with High Thermal Stability via Functionalized Sol Modification

1.
Department of Chemistry, TKL of Metal-and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China

Received Date: 2 April 2013
Available Online: 15 July 2013
Fund Project: 国家自然科学基金(No.21071086,21301098) (No.21071086,21301098)天津市自然科学基金青年项目(No.13JCQNJC02000) (No.13JCQNJC02000)“111计划”(No.B12015) (No.B12015)“国家大学生创新性实验计划”(No.111005510)资助项目。 (No.111005510)

By using hydrogen titanate nanotubes as support and titanium sol containing copper(Ⅱ) acetate as modifying agent, CuO modified-TiO₂ nanotubes (CuO/TiO₂ NTs) with high thermal stability were prepared by impregnation method. The prepared materials were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), N₂ absorption-desorption (BET), and temperature programed desorption (TPD). The catalytic performances for CO oxidation of the obtained samples were evaluated. Obtained results show that not only is the copper component coated on the nanotubes, but also the thermal stability of the tubular support is improved after the impregnation process. The influences of support form, atomic ratio of Cu to Ti, and calcination temperature on the catalytic performance of the prepared catalysts were also investigated. Obtained results also indicate that the CuO/TiO₂ NTs (n_Cu:n_Ti=1:5) calcined at 400 ℃ exhibit the best catalytic performance.
- hydrogen titanate nanotubes;CuO;modification by functionalized sol;CO oxidation;catalytic activity
1. [1]
  [1] Min K, Song M W, Lee C H. Appl. Catal. A, 2003,251:143-156
2. [2]
  [2] Zheng X C, Wu S H, Wang S P, et al. Appl. Catal. A, 2005, 283:217-223
3. [3]
  [3] MAO Dong-Sen(毛东森), TAO Li-Hua(陶丽华), WANG Qian(王倩), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(3):447-452
4. [4]
  [4] Chary K V R, Sagar G V, Naresh D, et al. J. Phys. Chem. B, 2005,109:9437-9444
5. [5]
  [5] Zhou H B, Huang Z, Sun C, et al. Appl. Catal. B, 2012,125: 492-498
6. [6]
  [6] MU Jin(穆劲), CHEN Li-Li(陈丽莉), KANG Shi-Zhao(康诗钊), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28 (2):251-256
7. [7]
  [7] Ma X D, Feng X, He X, et al. Micropor. Mesopor. Mater., 2012,158:214-218
8. [8]
  [8] ZHANG Xue-Hong(张雪红), TANG Xing-Hua(唐星华), CHENG Xin-Sun(程新孙). Acta Phys.-Chim. Sin.(物理化学学报), 2006,22(5):532-537
9. [9]
  [9] QIN Liang-Sheng(秦亮生), YIN Dong-Hong(银董红), LIU Jian-Fu(刘建福), et al. Chinese J. Catal.(催化学报), 2005, 26(8):714-718
10. [10]
  [10] Cao J L, Wang Y, Zhang T Y, et al. Appl. Catal. B, 2008, 78:120-128
11. [11]
  [11] SHAO Qian(邵谦), WANG Xiao-Jie(王小杰), GE Sheng-Song(葛圣松), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(5):1043-1049
12. [12]
  [12] Yao B D, Chan Y F, Zhang X Y, et al. Appl. Phys. Lett., 2003,82(2):281-283
13. [13]
  [13] Kasuga T, Hiramatsu M, Hoson A, et al. Langmuir, 1998,14: 3160-3163
14. [14]
  [14] Doong R A, Chang S M, Tsai C W. Appl. Catal. B, 2013 (129):48-55
15. [15]
  [15] Xu S P, Du A J, Liu J, et al. Int. J. Hydrogen Energy, 2011, 36(11):6560-6568
16. [16]
  [16] Nian J N, Chen S A, Tsai C C, et al. J. Phys. Chem. B, 2006,110:25817-25824
17. [17]
  [17] Zhu B L, Zhang X X, Wang S R, et al. Micropor. Mesopor. Mater., 2007,102:333-336
18. [18]
  [18] Zhang M, Jin Z S, Zhang J W, et al. J. Mol. Catal. A, 2004, 217:203-210
19. [19]
  [19] Zhu B L, Li K R, Zhou J, et al. Catal. Commun., 2008,9 (14):2323-2326
20. [20]
  [20] An H Q, Zhu B L, Li J X, et al. J. Phys. Chem. C, 2008,112 (48):18772-18775
21. [21]
  [21] An H Q, Zhou J, Li J X, et al. Catal. Commun., 2009,11(3): 175-179
22. [22]
  [22] An H Q, Li J X, Zhou J, et al. J. Mater. Chem., 2010,20(3): 603-610
23. [23]
  [23] Chapelle A, Yaacob M H, Pasquet I, et al. Sensor Actuat. B, 2010,153:117-124
24. [24]
  [24] Yu J G, Ran J R. Energy Environ. Sci., 2011,4:1364-1371
25. [25]
  [25] Yu J G, Hai Y, Jaroniec M. J. Colloid Interf. Sci., 2011,357: 223-228
26. [26]
  [26] Sing K S W, Everett D H, Haul R A W, et al. Pure Appl. Chem., 1985,57:603-619
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
3. [3]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
7. [7]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
8. [8]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
10. [10]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
11. [11]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
12. [12]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
13. [13]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
14. [14]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
15. [15]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
16. [16]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
17. [17]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
20. [20]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(288)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Catalytic Performance for CO Oxidation of CuO Modified-TiO2 Nanotubes with High Thermal Stability via Functionalized Sol Modification

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Catalytic Performance for CO Oxidation of CuO Modified-TiO₂ Nanotubes with High Thermal Stability via Functionalized Sol Modification