Citation: XIE Run-Fang, YANG Xiang-Jun, HAN Yun-Shan, LI Shu-Hua. Solid Phase Extraction Gold from Alkaline Cyanide Solution with Benzyl Dimethyl Dodecyl Ammonium Chloride[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 487-491. doi: 10.11862/CJIC.2014.022 shu

Solid Phase Extraction Gold from Alkaline Cyanide Solution with Benzyl Dimethyl Dodecyl Ammonium Chloride

1.
1 School of Forensic Medicine, Kunming Medical University, Kunming 650500, China;

Received Date: 19 June 2013
Available Online: 11 July 2013
Fund Project: 国家自然科学基金(No.20471051)资助项目。 (No.20471051)

The benzyl dimethyl dodecyl ammonium chloride (BDMDAC) can react with Au(CN)₂^- to the ionic complex and the compound can be extracted quantitatively. At the same time, It can be enriched highly by solid phase extraction column of reversed phase bonded silica gel. Therefore, we proposed a new method of extracting gold with high enrichment multiple. What enriched by the solid phase extraction column can be eluted by ethanol and the gold in the eluent can be determinated with spectrophotometry. The solid phase extraction column was not easily damaged and it can repeat using. The method is used to extract trace amounts of gold from alkaline cyanide solution and the recovery rate of gold is higher than 98% under the optimal experimental condition.
- solid phase extraction;benzyl dimethyl dodecyl ammonium chloride(BDMDAC);alkaline cyanide solution;gold;separation
1. [1]
  [1] XIE Qi-Ying(谢琦莹), CHEN Jing (陈景),YANG Xiang-Jun(杨项军), et al. Chinese J. Inorg. Chem.(无机化学学报),2007,23(1):57-62
2. [2]
  [2] XIE Qi-Ying(谢琦莹), CHEN Jing (陈景), YANG Xiang-Jun (杨项军), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008,24(6):897-901
3. [3]
  [3] ZOU Lin-Hua(邹林华), CHEN Jing(陈景). Chin. J. Precious Metals(贵金属), 1995,16(4):61-67
4. [4]
  [4] HUANG Kun(黄昆), CHEN Jing(陈景), WU Jin-Guang(吴瑾光), et al. Chin. J. Nonferr. Metals(中国有色金属学报), 2001,11(2):307-311
5. [5]
  [5] HUANG Kun(黄昆),CHEN Jing(陈景), CUI Ning(崔宁), et al. Chin. J. Nonferr. Metals(中国有色金属学报), 2001, 11(3):518-521
6. [6]
  [6] YANG Xiang-Jun(杨项军), CHEN Jing(陈景), XIE Qi-Ying (谢琦莹), et al. Chin. J. Prog. Chem.(化学进展), 2009,21(7/ 8):1583-1591
7. [7]
  [7] YAN Wen-Fei(闫文飞), MA Gang(马刚), YAN Chun-Hua(严纯华), et al. Chin. J. Spectrosc. Spectr. Anal.(光谱学与光谱分析), 1999,19(6):806-810
8. [8]
  [8] LIU Yue-Ying(刘月英),CHEN Jing(陈景), XIE Qi-Ying(谢琦莹). Chin. J. Nonferr. Metals(中国有色金属学报), 2009,19 (7):1316-1321
9. [9]
  [9] XIE Run-Fang(解润芳), HUANG Feng(黄锋), WEI Qun-Yan(韦群艳), et al. Chin. J. Phys. Testing Chem. Anal. Part B (理化检验-化学分册), 2008,44(5):444-446
10. [10]
  [10] Hu Q F, Chen X B, Yang X J, et al. Anal. Sci., 2006,22: 627-630
11. [11]
  [11] Amin A S, Saber A L, Mohammed T Y. Spectrochim. Acta Part A, 2009,73:195-200
12. [12]
  [12] Rajesh N, Gurulakshmanan G. Spectrochim. Acta Part A, 2008,69:391-395
13. [13]
  [13] LIN Hong(林洪), ZHU Li-Ya(朱利亚), LI Hai-Tao(李海涛), et al. Chin. J. Precious Metals(贵金属), 2005,26(3):51-54
14. [14]
  [14] Yang G Y, Hu Q F, Yang J H, et al. Anal. Sci., 2003,19: 299-302
15. [15]
  [15] Qi D J, Kang X J, Chen L Q, et al. Anal. Bioanal. Chem., 2008,390:929-938
16. [16]
  [16] CHAI Yao-Dong(柴跃东), LI Ming(李明), YANG Yan(杨艳), et al. Chin. J. Gold(黄金), 2005,26(4):42-44
17. [17]
  [17] PAN Xue-Jun(潘学军), CHEN Jing(陈景). Chin. J. Rare Metals(稀有金属), 2000,24(2):90-95
18. [18]
  [18] Kocūrová L, Balogh I S, Škrlíková J, et al. Talanta, 2010, 82:1958-1964
19. [19]
  [19] Badiei Y M, Jiang Y B, Widger L R, et al. Inorg. Chem., 2012,382:19-26
20. [20]
  [20] Sandlin R D, Whelan C J, Samuel B M, et al. Inorg. Chem., 2012,391:135-140
21. [21]
  [21] PAN Xue-Jin(潘学军), CHEN Jing(陈景). Chin. J. Rare Metals(稀有金属), 1999,18(2):88-96
22. [22]
  [22] ZHANG Hai-Xia(张海霞), ZHU Peng-Ling(朱彭龄). Chin. J. Rev. Prog. Chem. Anal.(分析化学评述与进展), 2000,28 (9):1172-1180
23. [23]
  [23] Xie F, Dreisinger D. J. Hazard. Mater., 2009,169:333-338
24. [24]
  [24] Li X Y, Leopold K. Analy. Chem., 2012,84:4340-4349
25. [25]
  [25] WU Fang-Hua (吴芳华). Chin. J. Anal. Testing Techno. Instru.(分析测试技术与仪器), 2012,18(2):114-120
26. [26]
  [26] Ghiladi R A, Rheingold A L, Siegler M A, et al. Inorg. Chem., 2012,389:131-137
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沈阳化工大学材料科学与工程学院沈阳 110142