Citation: BAIYIN Meng-He, GANG Gang, NAREN Ji-Ru-Ga. Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 405-410. doi: 10.11862/CJIC.2014.012 shu

Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄

1.
1 College of Chemistry & Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China;

Corresponding author: BAIYIN Meng-He,
Received Date: 10 April 2013
Available Online: 5 October 2013
Fund Project:

Layered K₂CdSnS₄ (1) was synthesized solvothermally and characterized by X-ray single crystal diffraction. The crystals belong to the space group C2/c, with a=1.1021(5) nm, b=1.1030(5) nm, c=1.5151(10) nm, α=90°, β=100.416(12)°, γ=90°, V=1.8114(17) nm³, Z=8, D_c=3.209 g·cm^-3, M_r=437.60, μ=6.853 mm^-1, F(000)= 1600, λ=0.071073 nm, and the final R=0.1042 and wR=0.2008 for all observed reflections. The compound is comprised of sheets with adamantane-like [Cd₂Sn₂S₁₀]^8- units. UV-Vis reflectance spectrum of compound 1 reveals that 1 is a semiconductor with a band gap of 2.2 eV. CCDC: 424763.
- solvothermal synthesis;crystal structure;quaternary thiostannate;optical property
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沈阳化工大学材料科学与工程学院沈阳 110142

Solvothermal Synthesis and Crystal Structure of K2CdSnS4

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通讯作者: 陈斌, bchen63@163.com

Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄