Citation: Dong-mei Cui. Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts[J]. Acta Polymerica Sinica, ;2020, 51(1): 12-29. doi: 10.11777/j.issn1000-3304.2020.19142 shu

Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts

Dong-mei Cui ^,

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: Dong-mei Cui, dmcui@ciac.ac.cn
Received Date: 31 July 2019
Revised Date: 28 August 2019
Available Online: 23 October 2019

The homo- and co-polymerizations of polar and non-polar monomers, since they can remain the stereo-regularity of the non-polyolefin precursors and meanwhile introduce polar groups into the non-polar polyolefins to improve their surface properties or bring unpredicted new functionalities, have attracted great attention of both academia and industries. However, polar groups are Lewis-basic while the catalysts employed in the polymerizations are usually Lewis acidic, which are prone to interact with the catalytic metal center to poison the catalysts, thus the study on homo- and co-polymerizations has been a challenging project. To date, many achievements have been obtained, and the following research should focus on realizing the homopolymerizations of polar monomers, increasing the activity and insertion ratio of the polar monomer in the copolymers, regulating the polar monomer composition and distribution along the copolymer macromolecular chains and isolating high molecular weight and practically available products. In this review, we summarized the recent developments of our group on the homo- and co-polymerizations of polar monomers, in particular polar styrenes and conjugated dienes with styrene, ethylene, butadien, isoprene and other popular nonpolar olefins, aiming to provide the readers novel strategies for designing new catalysts and polar monomers, as well as the unprecedented mechanisms.
- Rare-earth metal catalyst,
- Coordination polymerization,
- Polar monomer,
- Conjugated dienes,
- Polyolefin
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