Citation: Hao Yin, Yan-zhe Song, Yun-feng Li, Meng-cheng Du, Jian-guang Pang, Xin-yan Shi. Study on Adhesion Mechanism of Resorcinol Formaldehyde Cobalt Salt Adhesive System in Tire Skeleton Materials[J]. Acta Polymerica Sinica, ;2020, 51(4): 411-420. doi: 10.11777/j.issn1000-3304.2019.19184 shu

Study on Adhesion Mechanism of Resorcinol Formaldehyde Cobalt Salt Adhesive System in Tire Skeleton Materials

1.
Key Laboratory of Rubber and Plastic Materials and Engineering, Ministry of education, Qingdao University of Science & Technology, Qingdao 266042
2.
Shandong Yanggu Huatai Chemical Co., Ltd., Yanggu 252300

Corresponding author: Xin-yan Shi, lindashi88@hotmail.com
Received Date: 17 October 2019
Revised Date: 30 December 2019
Available Online: 20 March 2020

Figures(14)

The strong adhesion between the rubber and the skeleton material determines the performance of the tire. Most of the damage such as puncture, fatigue, and delamination of the tire are caused by the failure of the adhesion between the rubber and the skeleton material. The adhesion of the material is directly related to the performance and life of the tire. In order to verify and further explore the mechanism of adhesion of the adhesive resin and cobalt salt to the tire and the copper-plated steel cord, the conventional adhesive resin R80 and two new adhesive resins HT1005 and H620 were selected to analyze the mechanism of adhesion through structural analysis, rubber vulcanization characteristics, T extraction test, a new adhesive layer strength test method and adhesive layer characterization method. The results show that the polar adhesive resin containing hydroxyl groups will be auto-phase-separated due to thermodynamic incompatibility with the polarity difference of non-polar natural rubber when vulcanized. The adhesive resin migrates to the interface layer between the rubber and the copper-plated steel wire, producing a resin-rich layer between the rubber and the copper-plated steel wire. Since the crosslinking temperature of the binder resin is about 140 °C, synchronous crosslinking reaction will occur in natural rubber vulcanization reaction. The network modulus of the binder resin is higher than that of the rubber vulcanization network, which will enhance the adhesion strength between the copper-plated steel wire and the rubber, and form a modulus transition layer between the copper-plated steel wire and the rubber. A modulus transition layer between the rubber and the rubber further enhances the adhesive layer.
- Copper-plated steel wire,
- Adhesive resin,
- Cobalt salt,
- Bonding mechanism
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1.
沈阳化工大学材料科学与工程学院沈阳 110142