Citation: Xia-tong Qin, Gen-qi Liu, Chen-hui Liu, Jian-xun Liu, Huan-huan Li, Yun-lei Cao, Xiao-dong Fan. Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel[J]. Acta Polymerica Sinica, ;2020, 51(2): 191-197. doi: 10.11777/j.issn1000-3304.2019.19170 shu

Cationic Surfactant Sensor Based on Poly(acrylic acid) Two-dimensional Photonic Crystal Hydrogel

Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710129

Corresponding author: Gen-qi Liu, liugenqi@nwpu.edu.cn
Received Date: 18 September 2019
Revised Date: 16 October 2019

A polyacrylic acid two-dimensional photonic crystal hydrogel (PAA 2D-PCH) was prepared with acrylic acid as monomers, ethylene glycol dimethylacrylate as cross-linkers, 2,2-diethoxyacetophenone as initiators and polystyrene two-dimensional photonic crystal with bright diffraction under visible light illumination as a template, and its stimulating response properties to cationic surfactants were investigated. The results indicated that the PAA 2D-PCH had a sensitive response to cationic surfactants, while no response to anion, nonionic and zwitterionic surfactants. When the concentration of CPC, CPB and CTAB was increased from 0 to 4 × 10⁻³ mol/L, the diameter of Debye ring increased by 5.95, 5.50 and 4.95 cm, respectively, and the particle spacing decreased by 390, 364, and 341 nm, respectively. In the anionic surfactant, nonionic surfactant and zwitterionic surfactant solution, the diameter of Debye ring of the PAA 2D-PCH showed almost no change. The selective recognition of cationic surfactants by PAA 2D-PCH stemed from the electrostatic interaction between the negatively charged carboxylate ions and the cationic surfactants in the phosphate buffer solution of pH = 7.4, causing the PAA 2D-PCH shrunk, the particle spacing reduced, the diameter of the Debye ring increased, and the diffraction wavelength blue shifted. Study on the response behavior of PAA 2D-PCH to cationic surfactants by Debye ring method is easy to operate and has the characteristics of reusability and visualization, which is expected to be used for the determination of cationic surfactants in water.
- Cationic surfactant,
- Two-dimensional photonic crystal,
- Polyacrylic hydrogel,
- Debye ring,
- Sensor
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