Citation: Yan Peng, Yu-jia Hou, Qiao-qiao Shen, Hui Wang, Gang Li, Guang-su Huang, Jin-rong Wu. Synthesis and Performance of a Double Network Self-healing Elastomer Based on Hydrogen Bonds and Diels-Alder Crosslinks[J]. Acta Polymerica Sinica, ;2020, 51(2): 158-165. doi: 10.11777/j.issn1000-3304.2019.19140 shu

Synthesis and Performance of a Double Network Self-healing Elastomer Based on Hydrogen Bonds and Diels-Alder Crosslinks

Yan Peng ^1,† ,
Yu-jia Hou ^1,† ,
Qiao-qiao Shen ¹ ,
Hui Wang ² ,
Gang Li ² ,
Guang-su Huang ¹ ,
Jin-rong Wu ^1,,

1.
State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering,Sichuan University, Chengdu 610065
2.
Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu 610041

Corresponding author: Jin-rong Wu, wujinrong@scu.edu.cn
Received Date: 31 July 2019
Revised Date: 23 August 2019

Intrinsic self-healing elastomers, which can automatically heal themselves after damage without the addition of other reagents, have recently attracted increasing attention. However, a trade-off commonly exists between high mechanical properties and high self-healing efficiency, which is always the bottle-neck in advancing these high performance self-healing elastomers. To solve this problem, a high performance and high self-healing efficiency elastomer was developed in this work based on hydrogen bonds and Diles-Alder (DA) crosslinks. Firstly, a monomer (HM) functionalized with amido bond and carbamic acid ester for the generation of hydrogen bonds was synthesized by N-butyl isocyanate and N-(2-hydroxyethyl)acrylamide. Next, one-pot free-radical copolymerization of HM, butyl acrylate (BA), and furfuryl methacrylate (FMA) was carried out to afford a linear copolymer, which was only cross-linked with hydrogen bonds. Finally, bismaleimide (BMI) was used to crosslink the linear copolymer through DA reaction. A double network self-healing elastomer with two kinds of crosslinks, i.e. hydrogen bonds and DA bonds, was thus prepared. The heating-up and cooling down FTIR spectroscopy was used to characterize the hydrogen bonds, while the existence of DA bonds was proved by FTIR, DSC, and DMA techniques. When an external force was applied, the hydrogen bonds broke firstly to dissipate energy, which helped to increase the toughness by about 6.2 times, the tensile strength by about 12.3 times, and Young’s modulus of the elastomer by about 26 times. Meanwhile, DA crosslinks endowed the elastomer with certain elasticity and the capability of fast shape recovery. Moreover, thanks to the reversible ability of hydrogen bonds and DA crosslinks, the elastomer exhibited a high self-healing efficiency up to 98%.
- Mechanical properties,
- Self-healing,
- Elastomer,
- Double networks
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