Citation: Zi-wei Si, Yu-feng Tian, Jing Zhao, Wei Zhang. Fabrication of a Janus Single-layered Covalent Organic Framework[J]. Acta Polymerica Sinica, ;2019, 50(3): 319-326. doi: 10.11777/j.issn1000-3304.2019.18234 shu

Fabrication of a Janus Single-layered Covalent Organic Framework

Zi-wei Si ¹ ,
Yu-feng Tian ¹ ,
Jing Zhao ^2,, ,
Wei Zhang ^1,,

1.
South China Advanced Institute for Soft Matter Science and Technology, South China University Technology, Guangzhou 510000
2.
School of Pharmaceutical Sciences, Guangzhou Medical University, Guangzhou 510182

Corresponding author: Jing Zhao, zhaojing@gzhmu.edu.cn Wei Zhang, weizhang@scut.edu.cn
Received Date: 7 November 2018
Revised Date: 22 November 2018
Available Online: 29 December 2018

Breaking the out-of-plane symmetry of 2D materials, which results so-called janus 2D materials, will endow them different physical and chemical properties, and thus will further enrich their applications in different fields. In this work, we designed and fabricated a Janus single-layered covalent organic framework using an amphiphilic planar molecule (truxene), which having different chians at both sides, as monomer. This amphiphilic truxene derivative is prepared by functionalization at its three active methylene positions with hydrophilic and hydrophobic chains, respectively. Since methylene carbon is a sp³ carbon, the induced hydrophobic and hydryphilic chains are located perpendicular to the phenyl ring in truxene. After poly-condensation reaction with p-phenylenediamine at water/dichlormethane interface, a colorless membrane is formed. Fourier transform infrared spectroscopy (FTIR) spectra of the product indicated the almost complete consumption of the starting materials and the formation of imine bond. Transmission electron microscopy (TEM) images of the resulting membrane show that, the shape of product is a well-defined plate like nano-structure. Further investigation through atomic force microscopy (AFM) measurement confirmed the products from the interface consists of film with ~1 nm in thickness, corresponding to the thickness of a single-layered covalent organic framework. Due to the templating effect of water and oil interface, the hydrophilic and hydrophobic chains are orientated to water and oil phase during the poly-condensation reaction, respectively. After the formation of single layered COF, these chains are fixed at different surfaces of the resulting COF. As a consequence, the obtained COF possesses a single layered structure with two different surfaces, in another word, is a Janus covalent organic framework. Demonstrated by contact angle experiments, two surfaces of this Janus COF show different affinities to water droplets.
- Covalent organic framework,
- Janus single-layered covalent organic framework,
- Janus 2D material,
- Janus 2D polymer
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沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of a Janus Single-layered Covalent Organic Framework

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com