Citation: Zhi-qin Wang, Chun Feng, Chen Ma, Xiao-yu Huang. Facile Preparation and Diverse Applications of Polymer Brush[J]. Acta Polymerica Sinica, ;2018, 0(12): 1467-1481. doi: 10.11777/j.issn1000-3304.2018.18199 shu

Facile Preparation and Diverse Applications of Polymer Brush

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Chun Feng, cfeng@sioc.ac.cn Xiao-yu Huang, xyhuang@sioc.cn
Received Date: 13 September 2018
Revised Date: 10 October 2018
Available Online: 16 October 2018

Polymer brush generally refers to a kind of special macromolecular structures, of which polymer chains are densely tethered to another polymer chain (one-dimension, 1-D), the surface of a planar (two-dimension, 2-D), a spherical or a cylindrical (three-dimension, 3-D) solid matrice via stable covalent or non-covalent bond linkages, and can be divided into 1-D, 2-D, and 3-D polymer brushes, respectively, depending on the substrates. Different from the corresponding linear counterpart with similar molecular composition, 1-D polymer brush has some attractive properties including wormlike conformation, compact molecular dimension, and notable chain end effects due to its compact and densely grafted structure. The introduction of polymer chains onto the surface of a 2-D or 3-D matrix can not only improve surface-related properties of the matrix significantly, but also endow new functionalities with the obtained hybrid polymer brushes. Thus, polymer brush is of great interest in the fields of polymer and material science due to its potential applications in catalysis, nanolithography, biomineralization, drug delivery, medical diagnosis, optoelectronics, and so on. With the advent of living/controlled polymerization, organic, and supramolecular chemistry, a large number of 1-D, 2-D and 3-D polymer brushes have been prepared. However, the development of highly efficient synthetic protocols for the preparation of polymer brush with precisely controlled composition, structure, and functionality remains a key challenge. Herein, we summarize our recent efforts on the development of efficient methods to prepare 1-D, 2-D, and 3-D polymer brushes and the exploration of their potential applications in drug delivery, anti-fouling coating, catalysis, and lithium-ion battery.
- Polymer brush,
- Living/controlled polymerization,
- Monomer design,
- Crystallization-driven self-assembly,
- Polymer composite
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沈阳化工大学材料科学与工程学院沈阳 110142

Facile Preparation and Diverse Applications of Polymer Brush

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com