Citation: Chen Lin, Xu-ming Xie. Preparation of GO/PMMA Nanocomposites with Significantly Increased Properties through Metal Ion Coordination[J]. Acta Polymerica Sinica, ;2019, 50(2): 170-178. doi: 10.11777/j.issn1000-3304.2018.18178 shu

Preparation of GO/PMMA Nanocomposites with Significantly Increased Properties through Metal Ion Coordination

Chen Lin ,
Xu-ming Xie ^,

Key Laboratory of Advanced Materials, Department of Chemical Engineering, Tsinghua University, Beijing 100084

Corresponding author: Xu-ming Xie, xxm-dce@mail.tsinghua.edu.cn
Received Date: 13 August 2018
Revised Date: 13 September 2018
Available Online: 6 December 2018

Metal ion coordinated GO/PMMA composites have been prepared by melt method. The interfacial interaction between the nanofiller and the polymer matrix is significantly increased due to the coordination bonding. As a result, the mechanical and thermal properties of the composites are highly improved. To study the property variation with the change of metal ions and preparation methods, two different metal ions (Cu(II) and Fe(III)) were added into the GO/PMMA system, respectively, and the composites were prepared by two different methods—the direct-melt method and the master-batch method. Fourier transform infrared spectroscopy (FTIR), Raman spectra, X-ray diffraction (XRD), scanning electron microscopy (SEM), tensile test, and thermogravimetic analysis (TGA) were performed to study the structures and properties of the composites. The FTIR results showed that GO and PMMA are successfully bridged via coordination bonding, for the characteristic peaks showed obvious blue shifts. Raman spectra indicated that coordination causes no extra defect to the GO sheets. SEM images showed that the GO sheets could be homogeneously dispersed in PMMA through master-batch method, while a poor dispersion through direct-melt method. From the tensile test results, it could be seen that the composites prepared by master-batch method had a better mechanical performance than those prepared by direct-melt method because of the different dispersion states. Fe(III)-coordinated composites have better mechanical performance than Cu(II)-coordinated composites do, due to the higher valence state of iron ions. The Young’s modulus and tensile strength of Fe(III)-0.5 wt% GO/PMMA composite are 29.6% and 31.8%, respectively, higher than those of the composite with only GO, and 75.0% and 35.7%, respectively, higher than those of neat PMMA. The temperature of maximum weight loss of Fe(III)-0.5 wt% GO/PMMA is 26 °C higher than that of GO/PMMA, and 82 °C higher than that of neat PMMA. This metal ion coordination method is efficient and simple, and can easily bridge nanofillers and polymer matrixes containing polar groups. This approach opens up a new strategy for improving the performance of many kinds of nanocomposites.
- Graphene oxide,
- Coordination,
- PMMA,
- Nanocomposite,
- Tensile property
1. [1]
  Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306: 666 − 669 doi: 10.1126/science.1102896
2. [2]
  Nair R, Blake P, Grigorenko A, Novoselov K S, Booth T J, Stauber T, Peres N M R, Geim A K. Science, 2008, 320: 1308 − 1308 doi: 10.1126/science.1156965
3. [3]
  Ziegler K. Phys Rev B, 2007, 75: 233407 doi: 10.1103/PhysRevB.75.233407
4. [4]
  Weitz R T, Yacoby A. Nat Nanotechnol, 2010, 5: 699 − 700 doi: 10.1038/nnano.2010.201
5. [5]
  Geim A K. Science, 2009, 324: 1530 − 1534 doi: 10.1126/science.1158877
6. [6]
  Lee C, Wei X, Kysar J W, Hone J. Science, 2008, 321: 385 − 388 doi: 10.1126/science.1157996
7. [7]
  Jiang L, Shen X P, Wu J L, Shen K C. J Appl Polym Sci, 2010, 118: 275 − 279 doi: 10.1002/app.v118:1
8. [8]
  Shin H J, Kim K K, Benayad A, Yoon S M, Park H K, Jung I S, Jin M H, Jeong H K, Kim J M, Choi J H, Lee Y H. Adv Funct Mater, 2009, 19: 1987 − 1992 doi: 10.1002/adfm.v19:12
9. [9]
  Wang G, Yang J, Park J, Gou X, Wang B, Liu H, Yao J. J Phys Chem C, 2008, 112: 8192 − 8195 doi: 10.1021/jp710931h
10. [10]
  Pham V H, Cuong T V. Nguyen-phan T D, Pham D H, Kim E J, Hur S H, Shin E W, Kim S, Chung J S. Chem Commun, 2010, 46: 4375 − 4377 doi: 10.1039/c0cc00363h
11. [11]
  Xu Y, Hong W, Bai H, Li C, Shi G. Carbon, 2009, 47: 3538 − 3543 doi: 10.1016/j.carbon.2009.08.022
12. [12]
  Liang J, Huang Y, Zhang L, Wang Y, Ma Y, Guo T, Chen Y. Adv Funct Mater, 2009, 19: 2297 − 2302 doi: 10.1002/adfm.v19:14
13. [13]
  Yu D S, Kuila T, Kim N H, Lee J H. Chem Eng J, 2014, 245: 311 − 322 doi: 10.1016/j.cej.2014.02.025
14. [14]
  Chen J, Li Y, Zhang Y, Zhu Y. J Appl Polym Sci, 2015, 132: 42000
15. [15]
  Lin C, Liu Y T, Xie X M. Aust J Chem, 2014, 67: 121 − 126 doi: 10.1071/CH13339
16. [16]
  Pan L, Liu Y T, Xie X M, Zhu X D. Chem Asian J, 2014, 9: 1519 − 1524 doi: 10.1002/asia.v9.6
17. [17]
  Bai H, Li C, Wang X, Shi G. J Phys Chem C, 2011, 115: 5545 − 5551
18. [18]
19. [19]
  Zhong M, Liu X Y, Shi F K, Zhang L Q, Wang X P, Cheetham A G, Cui H G, Xie X M. Soft Matter, 2015, 11: 4235 − 4241 doi: 10.1039/C5SM00493D
20. [20]
  Liu Y T, Feng Q P, Xie X M, Xe X Y. Carbon, 2011, 49: 3371 − 3375 doi: 10.1016/j.carbon.2011.03.055
21. [21]
  Goncalves G, Marques P A A P, Timmons A B, Bdkin I, Singh M K, Emami N, Gracio J. J Mater Chem, 2010, 20: 9927 − 9934 doi: 10.1039/c0jm01674h
22. [22]
  Zhong M, Liu Y T, Xie X M. J Mater Chem B, 2015, 3: 4001 − 4008 doi: 10.1039/C5TB00075K
23. [23]
  Liu Y T, Tan Z, Xie X M, Wang Z F, Ye X Y. Chem Asian J, 2013, 8: 817 − 823 doi: 10.1002/asia.v8.4
24. [24]
  Jurow M, Manichev V, Pabon C, Hageman B, Matolina Y, Drain C M. Inorg Chem, 2013, 52: 10576 − 10582 doi: 10.1021/ic401563f
25. [25]
  Park S, Lee K S, Bozoklu G, Cai W, Nguyen S T, Ruoff R S. ACS Nano, 2008, 2: 572 − 578 doi: 10.1021/nn700349a
26. [26]
  Cong H P, Wang P, Yu S H. Small, 2014, 10: 448 − 453 doi: 10.1002/smll.v10.3
27. [27]
  Cong H P, Wang P, Yu S H. Chem Mater, 2013, 25: 3357 − 3362 doi: 10.1021/cm401919c
28. [28]
  Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y Y, Wu Y, Nguyen S T, Ruoff R S. Carbon, 2007, 45: 1558 − 1565 doi: 10.1016/j.carbon.2007.02.034
29. [29]
  Shen J F, Hu Y, Shi M, Lu X, Qin C, Li C, Ye M X. Chem Mater, 2009, 21: 3514 − 3520 doi: 10.1021/cm901247t
30. [30]
  Dreyer D R, Park S, Bielawski C W, Ruoff R S. Chem Soc Rev, 2010, 39: 228 − 240 doi: 10.1039/B917103G
31. [31]
  Vuluga D, Thomassin J M, Molenberg I, Huynen I, Gilbert B, Jerome C, Alexandre M, Detrembleur C. Chem Commun, 2011, 47: 2544 − 2546 doi: 10.1039/c0cc04623j
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
3. [3]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
6. [6]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
7. [7]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
8. [8]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-. doi: 10.1016/j.actphy.2025.100072
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
11. [11]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
12. [12]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
13. [13]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
14. [14]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
15. [15]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
16. [16]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
17. [17]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
18. [18]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
19. [19]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
20. [20]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(179)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142