Citation: Lu Chen, Zhen-hua Zhang, Shao-qiang Luo, Ying Gao, Chen Zhang, Liu-yun Hu, Miao Du, Yi-hu Song, Qiang Zheng. Rheological Behavior of Hydroxyethylacrylate/Sodium Acryloyldimethyl Taurate Copolymer Aqueous Solution[J]. Acta Polymerica Sinica, ;2019, 50(1): 91-98. doi: 10.11777/j.issn1000-3304.2018.18156 shu

Rheological Behavior of Hydroxyethylacrylate/Sodium Acryloyldimethyl Taurate Copolymer Aqueous Solution

Lu Chen ¹ ,
Zhen-hua Zhang ² ,
Shao-qiang Luo ² ,
Ying Gao ¹ ,
Chen Zhang ² ,
Liu-yun Hu ² ,
Miao Du ^1,, ,
Yi-hu Song ¹ ,
Qiang Zheng ¹

1.
Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027
2.
Infinitus (China) Company Ltd, Guangzhou 510623

Corresponding author: Miao Du, dumiao@zju.edu.cn
Received Date: 5 July 2018
Revised Date: 29 August 2018
Available Online: 19 October 2018

The rheological behaviors of hydroxyethylacrylate/sodium acryloyldimethyl taurate copolymer (EMT-10) in aqueous solution have been investigated systematically. EMT-10 has been widely used as a cosmetics thickener for its excellent emulsibility/stability at relatively low content; besides, its capability of persistent thickening effect over a broad variety of novel chemical structures is conducive to their perfect compatibility with specific active ingredients. Both pyrene fluorescence observation and rheological behavior revealed that hydrogen bonding and electrostatic interactions could enhance the intramolecular hydrophobic associations among EMT-10 macromolecules in the solution system, which led to the formation of hydrophobic microdomains within EMT-10 molecules even at ultra-low concentration. In the meantime, EMT-10’s thickening capability could be promoted by the synergism of these three interactions, i.e., intermolecular hydrophobic associations, hydrogen bonding interaction, and electrostatic interaction. The viscosity of EMT-10 aqueous solution exhibited higher scaling value against concentration than neutral polymer and polyelectrolyte solutions did in the unentangled semidilute solution and entangled semidilute solution regions. Moreover, it was insensitive to temperature due to the counteracting effect between hydrophobic interaction and hydrogen bonding interaction. Yielding occurred when solution concentration was higher than 0.3 wt% and the yielding stress increased with mounting concentration. Dual yielding behaviors showed up at solution concentration above 1 wt%, of which the second yielding was related to the formation and breakup of clusters that resulted from intramolecular hydrophobic associations and hydrogen bonding interaction under high shearing. Various additives could affect the rheological behaviors of EMT-10 solution remarkably. Viscosity of 1.5 wt% EMT-10 solution decreased with the addition of surfactants, urea, and salt, among which salt exhibited a sharp reducing effect. Compared with poly(vinyl alcohol) and poly(ethylene oxide), EMT-10 implicated strong intermolecular interactions including chain entanglements, electrostatic interaction, hydrophobic interaction, and hydrogen bonding interaction.
- Rheological behavior,
- Hydrogen bonding interaction,
- Hydrophobic association,
- Electrostatic interaction
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1.
沈阳化工大学材料科学与工程学院沈阳 110142