Citation: Guo-song Chen, Ping Yao, Dao-yong Chen. Further Expansions and Applications of the Principles and Methodology of Non-covalent Connected Micelles[J]. Acta Polymerica Sinica, ;2018, 0(8): 1048-1065. doi: 10.11777/j.issn1000-3304.2018.18064 shu

Further Expansions and Applications of the Principles and Methodology of Non-covalent Connected Micelles

The State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438

Corresponding author: Guo-song Chen, guosong@fudan.edu.cn Ping Yao, yaoping@fudan.edu.cn Dao-yong Chen, chendy@fudan.edu.cn
Received Date: 14 February 2018
Revised Date: 10 April 2018
Available Online: 28 June 2018

At the end of the last century, Professor Jiang Ming et al. succeeded in fabricating regular nanostructures through localizing interactions in the systems of polymer complexes. Through continuous expansion and deepening of this principle and method, a new strategy of macromolecular self-assembly was established. This review summarizes recent developments and applications of non-covalently connected micelles (NCCMs), including: Introducing of new driving forces such as supramolecular interactions to drive the formation of NCCMs, providing the resultant NCCMs with new features and functions; Applying the principle to the self-assembly of biological macromolecules, thereby developing an entirely green route to self-assembly of macromolecules; Also, through localizing covalent crosslinking reaction of one block of a diblock copolymer, we realized micellization of the block copolymer in its common solvent induced by the crosslinking reaction, resulting in highly efficient fabrication of core-stabilized micelles as well as a new pathway for controlling the kinetics of polymer micellization, the structures and the properties of the polymeric micelles.
- Non-covalent connected micelles,
- Macromolecular self-assembly,
- Supramolecular interactions,
- Non-covalent bonds,
- Biomacromolecular self-assembly
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