调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构

引用本文: 林瑞崇, 郭绍伟. 调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构[J]. 高分子学报, 2018, 0(8): 1016-1032. doi: 10.11777/j.issn1000-3304.2018.18020 shu

Citation: Ruey-Chorng Lin, Shiao-Wei Kuo. Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures[J]. Acta Polymerica Sinica, 2018, 0(8): 1016-1032. doi: 10.11777/j.issn1000-3304.2018.18020 shu

调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构

林瑞崇 ,
郭绍伟 ^,

台湾中山大学材料与光电科学学系　高雄 80424

通讯作者: E-mail: kuosw@faculty.nsysu.edu.tw

摘要: 调控嵌段共聚物共混体系的氢键作用力可应用在光学、电性及生物医用领域，因此吸引了高分子科学家广泛的研究兴趣，它提供了制备新型高分子材料(包含可调性及响应性的功能)的方法. 在此篇综述中，我们整理了各种氢键作用力调控嵌段共聚物共混体系(如嵌段共聚物/低分子量化合物、嵌段共聚物/均聚物及嵌段共聚物/嵌段共聚物混合体系)在固态及液态的自组装行为.

关键词:

English

Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures

Ruey-Chorng Lin ,
Shiao-Wei Kuo ^,

Department of Materials and Optoelectronic Science, Center for Functional Polymers and Supramolecular Materials, Taiwan Sun Yat-Sen University, Kaohsiung 80424

Corresponding author: Shiao-Wei Kuo, E-mail: kuosw@faculty.nsysu.edu.tw

Received Date: 16 January 2018
Revised Date: 23 February 2018
Available Online: 01 August 2018

Abstract: Self-assembly from block copolymers is a bottom-up process, a relatively inexpensive and simple approach for the preparation of large-scale nano-patterns. This self-assembly from diblock copolymers is driven by the combination of repulsive and attractive interactions due to the covalent bond linkage. The intrinsic immiscibility or incompatibility among the A or B block segments possesses the repulsive force and then confines into nanoscaled domain through the microphase separation because of the attractive force from the covalent bond linkage of A and B block segments. In general, these diblock copolymers can form different well-defined nanostructures in the bulk state including alternative lamellae, bicontinuous double gyroid, hexagonally packed cylinder, and body-centered cubic (BCC) structures, depending on the relative volume fractions of the block copolymer segments, interaction parameters (χ), and degrees of polymerization (N). However, the preparation of block copolymers with controlled volume fraction would be complicated and time-consuming; thus the diblock copolymers (A-b-B) blending with their homopolymer or low-molecular-weight compound would be an easier method for preparing different self-assembled nanostructures. Therefore, self-assembly nanostructures of block copolymer mixtures through mediated hydrogen bonding interactions have attracted much interest in polymer science because of their potential applications in photonic, electronic and biomedical fields, which could offer the unique possibility to create new functional polymeric materials with tunable and responsive behaviors. In this review article, we describe the self-assembly nanostructure of the block copolymer mixtures including block copolymer/low molecular weight compound, block copolymer/homopolymer, and block copolymer/block copolymer mixtures in bulk and solution states by mediated hydrogen bonding strength. Mediated strength of hydrogen bonding in block copolymer blending with homopolymer or block copolymer could provide order-order phase transition from typical lamellar, double gyroid, cylinder, and BCC spherical structure, even various hierarchical self-assembly structures such as three-phase lamellae, core-shell cylinder, and cylinder in lamellae structures in bulk state. Furthermore, it also possesses the different micellar structures of block copolymer mixtures such as spheres, rods, vesicles, and even large compound micelles in solution state.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构

通讯作者: E-mail: kuosw@faculty.nsysu.edu.tw

English

Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures

Corresponding author: Shiao-Wei Kuo, E-mail: kuosw@faculty.nsysu.edu.tw

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构

通讯作者: E-mail: kuosw@faculty.nsysu.edu.tw

English

Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures

Corresponding author: Shiao-Wei Kuo, E-mail: kuosw@faculty.nsysu.edu.tw

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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