Citation: Dong-yang Chen, Cheng Liu, Jin-yan Wang, Chun-yue Pan, Gui-peng Yu, Xi-gao Jian. Research Progress on the Electrochemical Application of Nanoporous Organic Polymers[J]. Acta Polymerica Sinica, ;2018, 0(5): 559-570. doi: 10.11777/j.issn1000-3304.2017.17298 shu

Research Progress on the Electrochemical Application of Nanoporous Organic Polymers

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083
2.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Corresponding author: Gui-peng Yu, gilbertyu@csu.edu.cn
Received Date: 27 October 2017
Revised Date: 28 November 2017
Available Online: 1 March 2018

As new emerged polymer materials, nanoporous organic polymers (NOPs), derived completely from light elements, are featured by high surface areas, low skeleton densities, and good chemical and thermal stabilities, which have led to numerous potential applications in heterogeneous catalysis, gas storage, and separation. Furthermore, their versatile synthetic methodology, controllable pore structure and easy modification significantly accelerate their development. Recently, the applications of NOPs targeted for organic electronic devices and solid state sensors have drawn increasing attention. The study of NOP-based electrochemical sensor technologies has become a very active and robust research area, and is expected to provide high-performance technologies for electrode materials, electrocatalytic carrier, and electrochemical detection, etc. One potential advantage of these materials is derived from their porous robust frameworks with high accessible surface areas, which enable structural preservation and efficient metal uptake and diffusion. However, the weak electron transport and wettability of NOPs somewhat limit their practical application in electrochemistry. In response, novel strategies have been developed to enhance their conductivity and wettability, including the incorporation of heteroatoms, extending of the skeleton conjugation, and the introduction of metal sites into the porous networks. Especially, the introduction of heteroatoms into the electrode materials is the mostly utilized technology, because it not only enables the increase in conductivity, wettablity and electroactive surface area of the electrodes, but also endows the electrodes with high pseudocapacitance. Furthermore, pore-size engineering, i.e., enhancing microporosity and constructing hierarchical structure, is crucial to improve the electrochemical performance. Hierarchically porous materials used as electrode matrices appear to be much more favorable for mass loading and ion diffusion or transport, endowing them with technological importance for applications in energy storage and sensor applications. This study summarizes recent research progress of NOPs in electrochemical applications, focuses on rational design, pore engineering and the structure-electrochemical property relationship, and also prospects their future development.
- Nanoporous organic polymers,
- Electrode materials,
- Electrocatalysis,
- Electrochemical properties
1. [1]
  Cote A P, Benin A I, Ockwig N W, O’Keeffe M , Matzger A J, Yaghi O M. Science, 2005, 310(5751): 1166-1170 doi: 10.1126/science.1120411
2. [2]
  Budd P M, Ghanem B S, Makhseed S, Mckeown N B, Msayib K J, Tattershall C E. Chem Commun, 2004, 2(2): 230-231
3. [3]
  Davankov V A, Tsyurupa M P. React Polym, 1990, 13(1-2): 27-42 doi: 10.1016/0923-1137(90)90038-6
4. [4]
  Jiang J X, Su F, Trewin A, Wood C D, Campbell N L, Niu H. Angew Chem, 2008, 47(7): 8574-8578
5. [5]
  Xie Y, Wang T T, Liu X H, Zou K, Deng W Q. Nat Commun, 2013, 4(3): 1960
6. [6]
  Carta M, Malpass-Evans R, Croad M, Rogan Y, Jansen J C, Bernardo P, Bazzarelli F, McKeown N B. Science, 2013, 339(6117): 303-307 doi: 10.1126/science.1228032
7. [7]
  Lu W G, Sculley J P, Yuan D Q, Krishna R, Zhou H C. J Phys Chem C, 2013, 117(8): 4057−4061 doi: 10.1021/jp311512q
8. [8]
  Ghanem B S, Swaidan R, Eric L, Pinnau I. Adv Mater, 2014, 26(22): 3688-3692 doi: 10.1002/adma.v26.22
9. [9]
  Yoon S M, Srirambalaji R, Kim K. Chem Rev, 2012, 112(2): 1196-1231 doi: 10.1021/cr2003147
10. [10]
  Lin S, Diercks C S, Zhang Y B, Kornienko N, Nichols E M, Zhao Y B, Paris A R, Kim D, Yang P D, Yaghi O M, Chang C J. Science, 2015, 349(6253): 1208-1213 doi: 10.1126/science.aac8343
11. [11]
  Xu Y, Jiang D L. Chem Commun, 2014, 50(21): 2781-2783 doi: 10.1039/c3cc49669d
12. [12]
  Guo J, Xu Y H, Jin S B, Chen L, Kaji T, Honsho Y, Addicoat M A, Kim J, Saeki A, Ihee H, Seki S, Irle S, Hiramoto M, Gao J, Jiang D L. Nat Commun, 2013, 4(3776): 2736-2744
13. [13]
  Li P F, Schon T B, Seferos D S. Angew Chem Int Ed, 2015, 54(32): 9361-9366 doi: 10.1002/anie.201503418
14. [14]
  Liu X, Xu Y, Jiang D. J Am Chem Soc, 2012, 134(25): 8738-8741
15. [15]
  Das G, Biswal B P, Kandambeth S, Venkatesh V, Kaur G, Addicoat M, Thomas H, Sandeep V, Banerjee R. Chem Sci, 2015, 6(7): 3931-3939 doi: 10.1039/C5SC00512D
16. [16]
  Zhao J, Lai H W, Lyu Z Y, Jiang Y F, Xie K, Wang X Z, Wu Q, Yang L J, Jin Z, Ma Y W, Liu J, Hu Z. Adv Mater, 2015, 27(23): 3541-3545 doi: 10.1002/adma.v27.23
17. [17]
  Wang S, Wang Q Y, Shao P P, Han Y Z, Gao X, Ma L, Yuan S, Ma X J, Zhao J W, Feng X, Wang B. J Am Chem Soc, 2017, 139(12): 4258-4262 doi: 10.1021/jacs.7b02648
18. [18]
  Lee J S M, Wu T H, Alston B M, Briggs M E, Hasell T, Hu C C, Cooper A I. J Mater Chem A, 2016, 4(20): 7665-7673 doi: 10.1039/C6TA02319C
19. [19]
  Chandra S, Chowdhury D R, Addicoat M, Heine T, Paul A, Banerjee R. Chem Mater, 2017, 29(5): 2074-2080 doi: 10.1021/acs.chemmater.6b04178
20. [20]
  Xu F, Chen X, Tang Z W, Wu D C, Fu R W, Jiang D L. Chem Commun, 2014, 50(37): 4788-4790 doi: 10.1039/C4CC01002G
21. [21]
  Xu F, Jin S B, Zhong H, Wu D C, Yang X Q, Chen X, Wei H, Fu R W, Jiang D L. Sci Rep, 2015, 5: 8225-8230. doi: 10.1038/srep08225
22. [22]
  Yang D H, Yao Z Q, Wu D H, Zhang Y H, Zhou Z, Bu X H. J Mater Chem A, 2016, 4(47): 18621-18627. doi: 10.1039/C6TA07606H
23. [23]
  Yang X F, Dong B, Zhang H Z, Ge R, Gao Y A, Zhang H M. RSC Adv, 2015, 5(105): 86137-86143. doi: 10.1039/C5RA16235A
24. [24]
  Ghazi Z A, Zhu L Y, Wang H, Naeem A, Khattak A M, Liang B, Khan N A, Wei Z X, Li L S, Tang Z Y. Adv Energy Mater, 2016, 6(24): 1601250. doi: 10.1002/aenm.201601250
25. [25]
  Zheng J, Tian J, Wu D, Gu M, Xu W, Wang C, Gao F, Zhang J G, Liu J, Xiao J. Nano Lett, 2014, 14(5): 2345-2352. doi: 10.1021/nl404721h
26. [26]
  Fang Y, Lv Y Y, Che R C, Wu H Y, Zhang X H, Gu D, Zheng G F, Zhao D Y. J Am Chem Soc, 2013,135(4): 1524-1530. doi: 10.1021/ja310849c
27. [27]
  Shrma V, Khilari S, Pradhan D, Mohanty P. RSC Adv, 2016, 6(61): 56421-56428. doi: 10.1039/C6RA06252K
28. [28]
  Hu F Y, Wang J Y, Hu S, Li L F, Wang G, Qiu J S, Jian X G. Nanoscale, 2016, 8(36): 16323-16331. doi: 10.1039/C6NR05146D
29. [29]
  Lu G L, Zhu Y L, Xu K L, Jin Y H, Ren Z J, Liu Z N, Zhang W. Nanoscale, 2015, 7(43): 18271-18277. doi: 10.1039/C5NR05324B
30. [30]
  Chandra S, Kundu T, Kandambeth S, Babarao R, Marathe Y, Kunjir S M, Banerjee R. J Am Chem Soc, 2014, 136(18): 6570-6573. doi: 10.1021/ja502212v
31. [31]
  Mullangi D, Dhavale V, Shalini S, Nandi shyamapada, Collins S, Woo T, Kurungot S, Vaidhyanathan R. Adv Energy Mater, 2016, 6(13): 1600110. doi: 10.1002/aenm.201600110
32. [32]
  Nandi S, Singh S K, Mullangi D, Illathvalappil R, George L, Vinod C P, Kurungot S, Vaidhyanathan R. Adv Energy Mater, 2016, 6(24): 1601189. doi: 10.1002/aenm.201601189
33. [33]
  Palma-Cando A, Scherf U. ACS Appl Mater Interfaces, 2015, 7(21): 11127-11133. doi: 10.1021/acsami.5b02233
34. [34]
  Zhuang X D, Gehrig D, Forler N, Liang H W, Wagner M, Hansen M R, Laquai F, Zhang F, Feng X L. Adv Mater, 2015, 27(25): 3789-3796. doi: 10.1002/adma.v27.25
35. [35]
  Deblase C R, Silberstein E S, Truong T T, Abruna H D, Dichtel W R. J Am Chem Soc, 2013, 135(34): 16821-16824.
36. [36]
  Khattak A M, Ghazi Z A, Liang B, Khan N A, Iqbal A, Li L, Tang Z Y. J Mater Chem A, 2016, 4(42): 16312-16317. doi: 10.1039/C6TA05784E
37. [37]
  Zhuang X D, Zhang F, Wu D Q, Feng X L. Adv Mater, 2014, 26(19): 3081-3086. doi: 10.1002/adma.201305040
38. [38]
  Hao L, Ning J, Luo B, Wang B, Zhang Y B, Tang Z H, Yang J H, Thomas A, Zhi L J, J Am Chem Soc, 2015, 137(1): 219-225. doi: 10.1021/ja508693y
39. [39]
  Mulzer C R, Shen L, Bisbey R P, McKone J R, Zhang N, Abruna H D, Dichtel W R. ACS Cent Sci, 2016, 2(9): 667-673. doi: 10.1021/acscentsci.6b00220
40. [40]
  Bui M. P. N, Li C. A, Han K N, Pham X H, Seong G H. Analyst, 2012, 137(8): 1888-1894. doi: 10.1039/c2an16020j
41. [41]
  Dong Y P, Zhou Y, Ding Y, Chu X F, Wang C M. Anal Methods, 2014, 6(23): 9367-9374. doi: 10.1039/C4AY01908C
42. [42]
  Li A, Lu R F, Wang Y, Wang X, Han K L, Deng W Q. Angew Chem Int Ed, 2010, 49(19):3330-3333. doi: 10.1002/anie.200906936
43. [43]
  Xu F, Hong X, Chen X, Wu D C, Wu Y, Liu H, Gu C, Fu R W, Jiang D L. Angew Chem Int Ed, 2015, 54(23): 6814-6818. doi: 10.1002/anie.201501706
44. [44]
  Fu X, Zhang Y D, Gu S, Zhu Y L, Yu G P, Pan C Y, Wang Z G, Hu Y H. Chem Eur J, 2015, 21(38): 13357-13363. doi: 10.1002/chem.v21.38
45. [45]
  Chen D Y, Gu S, Fu Y, Zhu Y L, Liu C, Li G H, Yu G P, Pan C Y. Polym Chem, 2016, 7(20): 3416-3422. doi: 10.1039/C6PY00278A
46. [46]
  Zhao W X, Hou Z S, Yao Z Q, Zhuang X D, Zhang F, Feng X L. Polym Chem, 2015, 6(40): 7171-7178. doi: 10.1039/C5PY01194A
47. [47]
  Wang P Y, Wu Q, Han L F, Wang S, Fang S M, Zhang Z H, Sun S M. RSC Adv, 2015, 5(35): 27290-27294. doi: 10.1039/C5RA02251G
48. [48]
  Roberts A D, Li X, Zhang H F. Chem Soc Rev, 2014, 43(13): 4341-4356. doi: 10.1039/C4CS00071D
49. [49]
  Li Z H, Wu D C, Huang X, Ma J H, Liu H, Liang Y R, Fu R W, Matyjaszewski K. Energy Environ Sci, 2014, 7(9): 3006 -3012. doi: 10.1039/C4EE00941J
50. [50]
  Yang X W, Zhuang X D, Huang Y J, Jiang J Z, Tian H, Wu D Q, Zhang F, Mai Y Y, Feng X L. Polym Chem, 2015, 6(7): 1088-1095. doi: 10.1039/C4PY01408A
51. [51]
  Li Y Q, Roy S, Ben T, Xu S X, Qiu S L. Phys Chem Chem Phys, 2014, 16(25): 12909-12917. doi: 10.1039/c4cp00550c
52. [52]
  Eliad L Salitra G, Soffer A, Aurbach D. J Phys Chem B, 2001, 105(29): 6880-6887. doi: 10.1021/jp010086y
53. [53]
  Eliad L, Salitra G, Soffer A, Aurbach D. J Phys Chem B, 2002, 106(39): 10128-10134. doi: 10.1021/jp020336q
1. [1]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
2. [2]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
7. [7]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
10. [10]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . 电容去离子提锂技术中电极材料的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-. doi: 10.1016/j.actphy.2025.100089
11. [11]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
12. [12]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
13. [13]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
14. [14]
  Xueting Cao , Shuangshuang Cha , Ming Gong . 电催化反应中的界面双电层：理论、表征与应用. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-. doi: 10.1016/j.actphy.2024.100041
15. [15]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
16. [16]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
17. [17]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
18. [18]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
19. [19]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
20. [20]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(106)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142