Citation: Hao Wang, Li-yuan Song, Yun-sheng Ma, Ri-guo Wang, Ai-hua He. Structures and Properties of High Performance Passenger Car Radical Tire Tread Stock Modified with Trans-1, 4-poly(butadiene-co-isoprene) Copolymer[J]. Acta Polymerica Sinica, ;2018, (3): 419-428. doi: 10.11777/j.issn1000-3304.2017.17101 shu

Structures and Properties of High Performance Passenger Car Radical Tire Tread Stock Modified with Trans-1, 4-poly(butadiene-co-isoprene) Copolymer

Hao Wang ^1,2 ,
Li-yuan Song ¹ ,
Yun-sheng Ma ² ,
Ri-guo Wang ³ ,
Ai-hua He ^1,,

1.
Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-plastics(Ministry of Education), School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042
2.
Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Chambroad Chemical Industry Institute Co., Ltd., Binzhou 256500
3.
Shandong Huaju Polymer Material Co., Ltd., Binzhou 256500

Corresponding author: Ai-hua He, aihuahe@iccas.ac.cn; ahhe@qust.edu.cn
Received Date: 24 April 2017
Revised Date: 3 June 2017

As a novel generation synthetic rubber, trans-1, 4-poly(butadiene-co-isoprene) copolymer rubber (TBIR) was used in high performance passenger car radical (PCR) tire tread stock, the structures and properties of solution polymerized styrene butadiene rubber (SSBR)/cis-1, 4-poly-butadienere rubber (BR)/TBIR blends were studied. Compared with amorphous SSBR and BR, TBIR raw rubber showed greatly improved green strength, modulus and toughness due to its crystallizability. However, the enthalpy of the crystallization (ΔH), the melting temperature (T_m) and the glass transition temperature (T_g) of TBIR were significantly lower than those of trans-1, 4-polyisoprene (TPI) because of the decreased structure regularity of the polymer chains from the copolymerization of isoprene with butadiene. Blended with 30 phr carbon black and 45 phr silica, SSBR/BR/TBIR compounds with 10 -20 phr TBIR showed improved green strength, modulus at 100%, and hardness due to the crystallizability of TBIR. Blending TBIR with SSBR/BR, the scorch time (t_c10) and the optimum curing time (t_c90) of the compounds changed little. After vulcanization at 150 ℃, the obtained SSBR/BR/TBIR vulcanizates showed excellent physical, mechanical and dynamic properties, including greatly improved tensile fatigue resistance (4.6 to 6.3 times higher), increased compressive strength (21.4% to 23.1% higher), wear resistance (10.8% to 15.1% higher), wet skid resistance (13.6% to 40.4% higher) and relatively unchanged rolling resistance. Both transmission electron microscopy (TEM) and carbon black dispersity test showed that the filler dispersion level in SSBR/BR/TBIR blends increased by 7.3% to 10.9%, and the mean filler aggregate size reduced by 1.4 -2.7 mm. The crystalline TBIR, with relatively high green strength and modulus of TBIR compared with the other general rubber materials like SSBR and BR, endowed the SSBR/BR/TBIR vulcanizates with good filler dispersion, and finally contributed to the greatly improved tensile fatigue resistance, increased wear resistance, wet skid resistance, compressive strength, modulus etc. So TBIR as a novel synthetic rubber is expected to be used in PCR tire tread stock for high performance.
- Trans-1, 4-poly(butadiene-co-isoprene) copolymer rubber,
- High performance tire,
- Tread stock,
- Wet skid resistance,
- Wear resistance,
- Magic triangle
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沈阳化工大学材料科学与工程学院沈阳 110142