Citation: Rong Wang, Jie Zhang, Xin-hua Wan. Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly[J]. Acta Polymerica Sinica, ;2016, (4): 409-421. doi: 10.11777/j.issn1000-3304.2016.16037 shu

Helical Bulky Polystyrene DerivativesChiral Teleinduction and Self-assembly

1.
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Corresponding author: Xin-hua Wan, xhwan@pku.edu.cn
Received Date: 1 February 2016
Revised Date: 18 February 2016

Design and synthesis of novel optically active helical polymers are active subjects and frontiers in the field of polymer science.Optically active helical vinylterphenyl polymers are physically and chemically stable and are of potential applications in chiral recognition and asymmetric catalysis.In this review, the helix-sense-selective radical polymerization of vinylterphenyl monomers, chiral teleinduction in radical copolymerization, and self-assembly of amphiphilic block copolymers consisting of helical chains as rigid segments in solution and at the air/water interface are comprehensively introduced.The results obtained up to now are summarized and a short outlook on the development of optically active vinylaromatic polymers is provided.
- Chiral teleinduction,
- Helix,
- Optical activity,
- Helix-sense-selective radical polymerization,
- Block copolymer,
- Self-assembly
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
85. [85]
86. [86]
87. [87]
88. [88]
89. [89]
90. [90]
91. [91]
92. [92]
93. [93]
94. [94]
95. [95]
96. [96]
97. [97]
98. [98]
99. [99]
100. [100]
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