Citation: Liang Liao, Peng-fei Fei, Bo-wen Cheng, Jian-qiang Meng, Xiao-yu Hu, Jun Song. Fabrication and Antibacterial Properties of Cellulose Triacetate/Chitosan Reverse Osmosis Membrane[J]. Acta Polymerica Sinica, ;2018, 0(5): 607-616. doi: 10.11777/j.issn1000-3004.2017.17165 shu

Fabrication and Antibacterial Properties of Cellulose Triacetate/Chitosan Reverse Osmosis Membrane

Liang Liao ¹ ,
Peng-fei Fei ^2,3 ,
Bo-wen Cheng ^2,3,, ,
Jian-qiang Meng ^2,3 ,
Xiao-yu Hu ^3,4 ,
Jun Song ^2,3

2.
School of Material Science and Engineering, Tianjin Polytechnic University,
3.
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin 300387
4.
Tianjin Motimo Membrane Tech Co. Ltd., Tianjin 300457

Corresponding author: Bo-wen Cheng, bowen15@tjpu.edu.cn
Received Date: 22 June 2017
Revised Date: 4 August 2017
Available Online: 1 March 2018

Compared with conventional reverse osmosis membrane (RO) materials, cellulose acetate (CA) reverse osmosis membranes have attracted considerable attention due to their unique chlorine resistance. However, β-glucose units in the cellulose backbone of CA molecule are vulnerable to erosion and degradation by aquatic microorganisms. To improve the antibacterial performance of cellulose triacetate reverse osmosis membrane, cellulose triacetate/chitosan blend reverse osmosis membrane (CTA/CS-RO) were designed and prepared with CS as the antibacterial agent by phase inversion. The homogeneous CTA solutions containning 20 g·L⁻¹ CS in formic acid were casted with casting knife of 250 μm thickness and the asymmetrical CTA/CS-RO membranes were obtained after solvent evaporation, immersion precipitation process. The mass fractions of CS to CTA were selected to be 0.25%, 0.50%. 0.75%, 1.00% and 1.25%, respectively. The structure and performances of the obtained CTA/CS-RO membranes were characterized by various methods such as Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, water contact angle and X-ray diffraction spectroscopy. The red shift of the characteristic peak of C―O―C in FTIR spectra indicated the presence of hydrogen bonding between CTA and CS. The characteristic peak of N1s in XPS spectra indicated the migration of CS to the membrane surface during phase inversion. The SEM images showed that membrane thickness decreased with increasing CS concentration. The addition of CS improved the hydrophilicity, water flux and mechanical properties of CTA/CS-ROs. When the mass fraction of CS to CTA was within 0.75%−1.00%, CTA/CS-ROs showed high salt rejection (R > 90%) without siginificant changes in elongation at break and crystallinity. The dynamic contact antibacterial test results indicated that CTA/CS-ROs showed inhibitory effect on E. coli and S. aureus, which was improved by increasing the content of CS. When the mass fraction of CS to CTA was within 0.75% − 1.00%, CTA/CS-ROs possessed higher inhibition rate against E. coli (65% − 72.5%) than S. aureus (16% − 51%) due to the electrostatic attraction between the positive CS and gram negative E. coli.
- Cellulose triacetate,
- Chitosan,
- Reverse osmosis membrane,
- Blend,
- Antibacterial
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