Citation: Wang Li, Guo Zhao-xia, Yu Jian. Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 434-445. doi: 10.1007/s10118-017-1905-x shu

Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends

Wang Li ^a,b ,
Guo Zhao-xia ^c,, ,
Yu Jian ^c,,

a.
The State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China
b.
College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
c.
Key Laboratory of Advanced Materials, Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Guo Zhao-xia, guozx@mail.tsinghua.edu.cn Yu Jian, yuj@mail.tsinghua.edu.cn
Received Date: 25 August 2016
Revised Date: 6 October 2016
Accepted Date: 13 June 2017

The morphology of polyamide 6/poly(butylene terephthalate) (PA6/PBT, 70/30, W/W) blends filled with pristine Zinc oxide (ZnO) nanoparticles and ZnO surface-modified by γ-glycidoxypropyltrimethoxysilane (K-ZnO) was investigated. The incorporation of ZnO and K-ZnO by one-step compounding both resulted in a smaller size and narrower distribution of PBT domains and the effect of ZnO was greater than K-ZnO. To reveal the underlying mechanism, two-step compounding in which ZnO or K-ZnO was premixed with PA6 or PBT was conducted and the finest morphology was achieved when mixing PA6 with premixed PBT/ZnO. Transmission electron microscopy (TEM) demonstrated that ZnO was distributed in PBT in all cases and K-ZnO was enriched at the interface except when K-ZnO was premixed with PBT. ZnO and K-ZnO caused a deterioration in the melt rheological properties of PBT, which played a dominating role in the morphological changes. In addition, the interfacial localization of K-ZnO enhanced the dynamic rheological properties of PA6/PBT blends substantially.
- Zinc oxide,
- Polyamide 6,
- Poly(butylene terephthalate),
- Morphology,
- Rheology
1. [1]
  Macosko, C.W., Macromol. Symp., 2000, 149(1): 171 doi: 10.1002/(ISSN)1521-3900
2. [2]
  Wang, Y., Zhang, Q. and Fu, Q., Macromol. Rapid Commun., 2003, 24(3): 231 doi: 10.1002/marc.200390026
3. [3]
  Khatua, B.B., Lee, D.J., Kim, H.Y. and Kim, J.K., Macromolecules, 2004, 37(7): 2454
4. [4]
  Das, A.K., Suin, S., Shrivastava, N.K., Maiti, S., Mishra, J.K. and Khatua, B.B., Polym. Compos., 2014, 35(2): 273 doi: 10.1002/pc.v35.2
5. [5]
  Chandran, N., Chandran, S., Maria, H.J. and Thomas, S., RSC Adv., 2015, 5(105): 86265
6. [6]
  Elias, L., Fenouillot, F., Majesté, J.C., Alcouffe, P. and Cassagnau, P., Polymer, 2008, 49(20): 4378
7. [7]
  Liu, X.Q., Wang, Y., Yang, W., Liu, Z.Y., Luo, Y., Xie, B.H. and Yang, M.B., J. Mater. Sci., 2012, 47(11): 4620
8. [8]
  Wu, D.F., Zhang, Y.S., Zhang, M. and Yu, W., Biomacromolecules, 2009, 10(2): 417
9. [9]
  Bose, S., Bhattacharyya, A.R., Kodgire, P.V., Misra, A. and Pötschke, P., J. Appl. Polym. Sci., 2007, 106(5): 3394 doi: 10.1002/app.v106:5
10. [10]
  Hrnjak-Murgić, Z., Jelčić, Ž., Kovačević, V., Mlinac-Misăk, M. and Jelenčić, J., Macromol. Mater. Eng., 2002, 287(10): 684 doi: 10.1002/(ISSN)1439-2054
11. [11]
  Jiang, L., Liu, B. and Zhang, J.W., Ind. Eng. Chem. Res., 2009, 48(16): 7594 doi: 10.1021/ie900576f
12. [12]
  Li, Y.J. and Shimizu, H., Macromol. Rapid Commun., 2005, 26(9): 710 doi: 10.1002/(ISSN)1521-3927
13. [13]
  Zhang, B.Q., Ding, Y.F., Chen, P., Liu, C.Y., Zhang, J., He, J.S. and Hu, G.H., Polymer, 2005, 46(14): 5385
14. [14]
  Filippone, G., Dintcheva, N.T., Acierno, D. and Mantia, F.P.L., Polymer, 2008, 49(5): 1312
15. [15]
  Kong, M.Q., Huang, Y.J., Chen, G.L., Yang, Q. and Li, G.X., Polymer, 2011, 52(22): 5231
16. [16]
  Lee, S.H., Kontopoulou, M. and Park, C.B., Polymer, 2010, 51(5): 1147
17. [17]
  Laoutid, F., François, D., Paint, Y., Bonnaud, L. and Dubois, P., Macromol. Mater. Eng., 2013, 298(3): 328 doi: 10.1002/mame.201200047
18. [18]
  Zou, H., Wang, K., Zhang, Q. and Fu, Q., Polymer, 2006, 47(22): 7821
19. [19]
  Xiang, F.M., Shi, Y.Y., Li, X.X., Huang, T., Chen, C., Peng, Y. and Wang, Y., Eur. Polym. J., 2012, 48(2): 350 doi: 10.1016/j.eurpolymj.2011.11.013
20. [20]
  Zhang, L.Y., Wan, C.Y. and Zhang, Y., Compos. Sci. Technol., 2009, 69(13): 2212 doi: 10.1016/j.compscitech.2009.06.005
21. [21]
  Chen. J., Chen, P., Wu, L., Zhang, J. and He, J.S., Polymer, 2006, 47(15): 5402
22. [22]
  Paran, S.M.R., Naderi, G. and Ghoreishy, M.H.R., Appl. Surf. Sci., 2016, 382: 63
23. [23]
  23 Nofar, M., Heuzey, M.C., Carreau, P.J. and Kamal, M.R., Polymer, 2016, 98(SI): 353
24. [24]
  Mallakpour, S. and Nouruzi, N., J. Mater. Sci., 2016, 51(13): 6400 doi: 10.1007/s10853-016-9936-1
25. [25]
  Huang, S.J., Bai, L., Trifkovic, M., Cheng, X. and Macosko, C.W., Macromolecules, 2016, 49(10): 3911
26. [26]
  Durandish, M. and Alipour, A., Chinese J. Polym. Sci., 2013, 31(4): 660 doi: 10.1007/s10118-013-1262-3
27. [27]
  Lin, C.Y., Zuo, M., Lin, H.H., Liu, T. and Zheng, Q., Chinese J. Polym. Sci., 2015, 33(8): 1162 doi: 10.1007/s10118-015-1666-3
28. [28]
  Hong, R.Y., Chen, L.L., Li, J.H., Li, H.Z., Zheng, Y. and Ding, J., Polym. Adv. Technol., 2007, 18(11): 901 doi: 10.1002/(ISSN)1099-1581
29. [29]
  Yu, W., Lan, J.H., Wang, S.J., Fang, P.F. and Sun, Y.M., Polymer, 2010, 51(11): 2403
30. [30]
  30 Jose, J.P., Chazeau, L., Cavaillé, J.Y., Varughese, K.T. and Thomas, S., RSC Adv. 2014, 4(4): 31643
31. [31]
  Peng, G.R., Li, Q.S., Yang, Y.L. and Wang, H.F., J. Appl. Polym. Sci., 2009, 114(4): 2128
32. [32]
  Cao, W., Zhou, B., Liu, Y.H., Ma, X.Y., Liu, Y., Wang, Z.C. and Zhu, Y.C., Polym. Int., 2013, 62(3): 432
33. [33]
  Wong, M.H., Guenther, J., Sun, L.Y., Blümel, J., Nishimura, R. and Sue, H.J., Adv. Funct. Mater., 2012, 22(17): 3614 doi: 10.1002/adfm.v22.17
34. [34]
  Therias, S., Larché, J.F., Bussière, P.O., Gardette, J.L., Murariu, M. and Dubois, P., Biomacromolecules, 2012, 13(10): 3283 doi: 10.1021/bm301071w
35. [35]
  Díez-Pascual, A.M. and Díez-Vicente, A.L., ACS Appl. Mater. Interfaces, 2014, 6(13): 10132 doi: 10.1021/am501610p
36. [36]
  Díez-Pascual, A.M. and Díez-Vicente, A.L., ACS Appl. Mater. Interfaces, 2014, 6(5): 3729 doi: 10.1021/am500171x
37. [37]
  Murariu, M., Doumbia, A., Bonnaud, L., Dechief, A.L., Paint, Y., Ferreira, M., Campagne, C., Devaux, E. and Dubois, P., Biomacromolecules, 2011, 12(5): 1762 doi: 10.1021/bm2001445
38. [38]
  Ding, J.W., Zhu, S.Y., Zhu, T., Sun, W., Li, Q., Wei, G. and Su, Z.Q., RSC Adv., 2015, 5: 22935
39. [39]
  Scaffaro, R., Botta, L., La Mantia, F.P., Gleria, M., Bertani, R., Samperi, F. and Scaltro, G., Polym. Degrad. Stab., 2006, 91(10): 2265 doi: 10.1016/j.polymdegradstab.2006.04.019
40. [40]
  Jeziórska, R., Polym. Degrad. Stab., 2005, 90(2): 224 doi: 10.1016/j.polymdegradstab.2005.03.018
41. [41]
  van Dubin, M., van Gurp, M., Leemans, L., Walet, M., Aussems, M., Martin, P., Legras, R., Machado, A.V. and Covas, J.A., Macromol. Symp., 2003, 198(1): 135
42. [42]
  Lievana, E. and Karger-Kocsis, J., Macromol. Symp., 2003, 202(1): 59 doi: 10.1002/(ISSN)1521-3900
43. [43]
  Kim, S.J., Kim, D.K., Cho, W.J. and Ha, C.S., Polym. Eng. Sci., 2003, 43(6): 1298 doi: 10.1002/(ISSN)1548-2634
44. [44]
  Wang, L., Guo, Z.X. and Yu, J., Ind. Eng. Chem. Res., 2014, 53(1): 206 doi: 10.1021/ie4026133
45. [45]
  Zeng, Z., Yu, J. and Guo, Z.X., Macromol. Chem. Phys., 2004, 205(16): 2197 doi: 10.1002/(ISSN)1521-3935
46. [46]
  Bousmina, M., Ait-Kadi, A. and Faisant, J.B., J. Rheol., 1999, 43(2): 415
47. [47]
  Cheng, H.K.F., Sahoo, N.G., Pan, Y.Z., Li, L., Chan, S.H., Zhao, J.H. and Chen, G., J. Polym. Sci., Part B: Polym. Phys., 2010, 48(11): 1203 doi: 10.1002/polb.v48:11
48. [48]
  Médéric, P., Razafinimaro, T., Aubry, T., Moan, M. and Klopffer, M.H., Macromol. Symp., 2005, 221(1): 75 doi: 10.1002/masy.200550308
49. [49]
  Bancquart, S., Vanhove, C., Pouilloux, Y. and Barrault, J., Appl. Catal. A: Gen, 2001, 218(1-2): 1 doi: 10.1016/S0926-860X(01)00579-8
50. [50]
  Ferretti, C.A., Olcese, R.N., Apesteguía, C.R. and Cosimo, J.I.D., Ind. Eng. Chem. Res., 2009, 48(23): 10387 doi: 10.1021/ie9004783
51. [51]
  Lin, G.P., Lin, L., Wang, X.L., Chen, L. and Wang, Y.Z., Ind. Eng. Chem. Res., 2015, 54(4): 1285
52. [52]
  Kim, H. and Kang, H.J., Polym. Korea, 2006, 30(1): 22
53. [53]
  Taylor, G.I., Proc. R. Soc. Lond. A, 1934, 146(858): 501 doi: 10.1098/rspa.1934.0169
54. [54]
  Cox, R.G., J. Fluid Mech., 1969, 37(3): 601 doi: 10.1017/S0022112069000759
55. [55]
  Grace, H.P., Chem. Eng. Commun., 1982, 14(3-6): 225 doi: 10.1080/00986448208911047
56. [56]
  Debrujin, R.A., Dissertation, The Netherlands: Eindhoven University of Technology, 1989
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