Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C<sub>60</sub>-oligofluorene Conjugates

Citation: Fu-ai Teng, Feng-li Liu, Lu Han, Zheng-ju Zhu, Yi-fang Zhang, Zhi-jin Wu, Zhe-wen Han, Wen-bin Zhang, Hui Li. Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates[J]. Chinese Journal of Polymer Science, 2017, 35(4): 503-514. doi: 10.1007/s10118-017-1899-4 shu

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

通讯作者: , zwhan@ecust.edu.cn
, wenbin@pku.edu.cn
, lihui@ecust.edu.cn

English

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

Fu-ai Teng ^a, ,
Feng-li Liu ^a, ,
Lu Han ^a, ,
Zheng-ju Zhu ^a, ,
Yi-fang Zhang ^a, ,
Zhi-jin Wu ^a, ,
Zhe-wen Han ^{a,
,} ,
Wen-bin Zhang ^{b,
,} ,
Hui Li ^{a,
,}

a.
School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Center for Soft Matter Science and Engineering, Peking University, Beijing 100871, China

Corresponding author: Zhe-wen Han, zwhan@ecust.edu.cn Wen-bin Zhang, wenbin@pku.edu.cn Hui Li, lihui@ecust.edu.cn

Received Date: 06 September 2016
Accepted Date: 12 October 2016
Revised Date: 11 October 2016
Available Online: 01 April 2017
Fund Project:

Abstract: A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths (OF_n) to the different positions of the spherical[60]fullerene (C₆₀) through a rigid linkage. The conjugates were characterized by ¹H-NMR, ¹³C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C₆₀ and OF_n remained unchanged when different lengths of OF_n were attached to C₆₀. The electron affinities of the OF_n-C₆₀ conjugates were close to that of C₆₀, while slight electronic interaction was found between the two individual chromophores (C₆₀ and OF_n) in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OF_n to C₆₀. It presents a systematic study on the self-assembly, structure-property relationship, and potential technical applications of the conjugates.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

通讯作者: , zwhan@ecust.edu.cn
, wenbin@pku.edu.cn
, lihui@ecust.edu.cn

English

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

Corresponding author: Zhe-wen Han, zwhan@ecust.edu.cn Wen-bin Zhang, wenbin@pku.edu.cn Hui Li, lihui@ecust.edu.cn

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Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates

通讯作者: , zwhan@ecust.edu.cn , wenbin@pku.edu.cn , lihui@ecust.edu.cn

English

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates

Corresponding author: Zhe-wen Han, zwhan@ecust.edu.cn Wen-bin Zhang, wenbin@pku.edu.cn Hui Li, lihui@ecust.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

通讯作者: , zwhan@ecust.edu.cn
, wenbin@pku.edu.cn
, lihui@ecust.edu.cn

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