Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

Citation: Qian Du, Jing Shao, Yao Gao, Wei-li Li, Hong-kun Tian, Dong-hang Yan, Yan-hou Geng, Fo-song Wang. Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors[J]. Chinese Journal of Polymer Science, 2017, 35(4): 480-489. doi: 10.1007/s10118-017-1885-x shu

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

通讯作者: , yanhou.geng@tju.edu.cn

English

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

a.
School of Material Science and Engineering and Collaborative Innovation Centre of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China
b.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c.
The 46 th Institute of the Sixth Academy of China Aerospace Science & Industry Corporation, Hohhot 010010, China

Corresponding author: Yan-hou Geng, yanhou.geng@tju.edu.cn

Received Date: 31 August 2016
Accepted Date: 25 September 2016
Revised Date: 23 September 2016
Available Online: 01 April 2017
Fund Project:

Abstract: Three acceptor-donor-acceptor (A-D-A) conjugated oligomers, i.e., O1, O2 and O3, have been synthesized using diketopyrrolopyrrole (DPP) as an electron-acceptor unit, and naphtho[1, 2-b:5, 6-b']dithiophene (NDT), anthra[1, 2-b:5, 6-b']dithiophene (ADT) or dithieno[3, 2-b:3', 2'-b']naphtho[1, 2-b:5, 6-b']dithiophene (DTNDT) as electron-donor unit. These oligomers exhibit identical highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels, which were ca.-5.1 and-3.3 eV, respectively. Upon thermal annealing, all three oligomers formed thin films with ordered microstructures, and their organic thin film transistors (OTFTs) exhibited p-type transport behavior. The mobility was increased with an extension of the size of D-units. O3 showed the best OTFT performance with the mobility of up to 0.20 cm²·V^-1·s^-1. The film quality of O3 was improved by adding 1 wt% poly (methylmethacrylate) (PMMA). In consequence, the mobility of the O3-based devices was further enhanced to 0.30 cm²·V^-1·s^-1.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

通讯作者: , yanhou.geng@tju.edu.cn

English

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

Corresponding author: Yan-hou Geng, yanhou.geng@tju.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

通讯作者: , yanhou.geng@tju.edu.cn

English

Acceptor-Donor-Acceptor Conjugated Oligomers Based on Diketopyrrolopyrrole and Thienoacenes with Four, Five and Six Rings for Organic Thin-film Transistors

Corresponding author: Yan-hou Geng, yanhou.geng@tju.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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